Question
14. The rate of solvolysis of iodide 1 is 100 times faster than the rate of...

14. The rate of solvolysis of iodide 1 is 100 times faster than the rate of solvolysis of iodide 3. What explanation (with structures) can you provide for the difference in reaction rates. Use aromaticity concepts!!(5 pts) CHOH Rate 100 Rao
Answers
å-o-o The carbocation formed is in resonance with the oxygen present in ring, hence after complete conjugation the system turns out to be aromatic. This effect is missing in the second reaction which retards the rate of reaction in comaprison to the first one.
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