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Phulua sueeIytiu (24) prigbhotorEddtc% Edit & CrezteShiteZ13midtcrmI 2020d8Identify the reactants You would coupling rcactionSynthesize the following azo dye us...

Question

Phulua sueeIytiu (24) prigbhotorEddtc% Edit & CrezteShiteZ13midtcrmI 2020d8Identify the reactants You would coupling rcactionSynthesize the following azo dye using anKO,sS0,HiwueitWtIte the structute OARD Aud considlering - the reactlon schetue Elvcu belowa#Eo 745046oVilinony 2140

phulua sueeIytiu (24) prig bhotor Eddtc % Edit & Crezte Shite Z13midtcrmI 2020d8 Identify the reactants You would coupling rcaction Synthesize the following azo dye using an KO,s S0,H iwueit WtIte the structute OARD Aud considlering - the reactlon schetue Elvcu belowa #Eo 745046o Vilinony 2140



Answers

Suggest products for the reactions of (a) chloroethane with ethoxide, (b) iodomethane with potassium tert-butoxide, (c) methoxide with 2-chloro-2-methylpropane and (d) iso-propoxide with iodomethane. Draw the structure of each product.

Let's since synthesize each of the following. Let's emphasize for a one to die, bro. Mo Propane from propane. I'll start with propane. So this is our protein. And we're going to add to this beer too, which will produce C h three c h b o r. I see it too, b r And this year is 12 di promo. Uh, propane for be, uh, acid tone to pro pinon from an alcohol. So have the alcohol that were in use. Is this one here? Seeks three h beach three silvery using to no undergo oxidation, which would yield C H three c threes. Here is Oh, are, um to broke and known from an alcohol the alcohol were using. Must be to pro panel Proceed clear to synthesize hurt beautiful alcohol to muffle to propane all from an AL Keen hulking that we will use here is, um, to metal propane or to Bethel propane. Close water. The presence of acid which would give me C H two c three 63 c h three h. This is my It hurts Beautiful alcohol. And for D propane. OIC acid from an alcohol. Uh, we're gonna use propane, al, in the presence of potassium permanganate IDs which we yield our propane OIC acid

This is Thea answer to Chapter twelve. Problem number eighteen Fromthe Smith Organic chemistry Textbook on DH. So we're being asked to do the Oz beom tetroxide Sendai hydroxy elation of to stereo ice murmurs of to beauty. So it's Cece to beauty mean and trans tube. You teen? I apologize. I forgot to label this one, so all right, so the cyst is at the top Trains is at the bottom. And so when we do the oz me, um tetroxide Cyn Dai hydroxy elation to Sister Beauty NW. What we actually get is we only get this single molecule. Um and so I have drawn it both ways here because the the two alcohol's Khun ad from above the double bond, in which case you would get the one that have drawn on the left here. Or they could add from below the double bond, in which case you get the one that I've drawn on the right here. But if you were to flip the one on the right vertically ah, and then flip it horizontally, you would actually end up with the exact same one that you have left. So is only a single molecule here However, when you do the dye hydroxy elation, toothy trans tube you teen, you actually do get a pair of an ant humors, depending on whether or not on whether the osmium tetroxide come from the top or from the bottom of the double bond. And so, since you get a pair of an anti mers here and you get on Lee Ah, this single molecule here. So the stereo chemistry of these two outcomes are different on. Therefore, we can say that Osmond Tetroxide is a stereo Selective re agent on That is the answer to number eighteen.

Taking a look at general reactivity off our kids and all kinds in this podcast. So these sort of bonds are possible if we utilize the extra two p orbital's that we have present on our carbon atoms and so on. All keen is a double bond on an Al Qaeda is a triple bond. And here we're taking a look of some chemical transformations using an alky in structure. So our first chemical transformation we have h 30 plus in H 20 We generate alcohol structure. Next we have HBR hydrogen bromine. We have the edition about Brahman atom. Next, we have a L to h 20 generate the following product. Lastly, we have one more chemical transformation where, firstly, we treat with BH three and th and then our second start is H 202 on HR minus. What does yield is he following structure the primary alcohol

Let's specify the missing compounds and a re agents in the following sin Theses for a we have Trans five method to heck scene to two methods. Heck, scene and we're missing the Regent's for this reaction. So in order for this reaction to take place, this is done, uh, in terms of a hydrogenation terms of hydrogen gas and a platinum catalyst along with the presence of ethanol for be. We are starting with this molecule here and double bond. And again, the re agents are unknown. And this is going to end up with small a cure here and the reemergence in this case it would be, um, plus each to, uh, palladium catalyst and also in the presence of ethanol 25 degrees Celsius. One atmosphere pressure for C ah were asked, um, what evidence in a higher spectrum of each of the crude products from the above, reactions would indicate the presence of one of the organic reactions used to synthesize the target molecule. So in each, the reactions, um, the reactant since each have a C C double bond on this is in the ire region, we'll see this as um stretching in the 16 20 to 16 80 centimeter region and the 3000 and 10 Thio 3095 centimeter region


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