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What is the product of the following reaction?...

Question

What is the product of the following reaction?

What is the product of the following reaction?



Answers

What are the products of the following reactions?

This question asked us to draw the products of each of these reactions. These air, both deals, older reactions. So just to quickly recap a deal's older reaction, we have a dying and a dying A file these air, the simplest two examples of those, and we'll have some electrons moving around here. So this will move over here. This move over here in this back here, and we will always get a six member ring with a one single pi bon left over on the dying side. Um, and so I'm gonna orient each of these in this way to make it easier to see. So for part A, we have a five member green here that has already oriented correctly, and then our dining are joining file. Looks like this. And then we have this key tone coming off of it like this. So if we do that reaction here, this comes here. This comes here and that goes back there were going to get a bicycle IQ, um, ring. So first we have our six number ring that we always get with. That one double bond looked over on the dying side. Um, and then the leftover carbon from If I remembered, ring will just be in the middle. So it's like this and then the rest of Dinah file it's just right over here like this. So that is one way to draw. It will also often see these drawn in this sort of, um, drawings. And then this one up here is the other end of the remembered ring. This is where our Dina filed waas. And then we have, um, that key tone over here. So either one of those ways of drawing this product is correct. And then for part B will do the same thing. So we have our dying already in the correct confirmation, and then we'll put our Diana file like that here. This is the same Diana file we had in a part. A. And so we'll do that same electron movement like this. So we'll get a new a six numbered ring with that double bond left over. We have the rest of that old one between those two car end carbons, and then we have the rest of the Diana file. Or you can draw this one in that other confirmation as well. So it would look like this, which have two carbons up top now. And, um, that key tone the left over. Over here. So again, two ways to draw this product.

I've got two different reactions that I'll just like to talk through very briefly. We've got the fast run up on the screen. So here we're attacking the carbon that is bonded to the Boram to this carbon that is bonded to the halogen. Therefore, we maintain the configuration about that double bond. As you concede, we have trans confirmation here in our final product. Now, in our second example, you can see that we have the cyst confirmation and the starting material. And then we take our free agents on other starting materials, and we retain that sis confirmation that we had in our starting material in our final product.

So in reactions while we're using a royal organa, boron and vinyl. Hey, light. The carbon that was bonded to a halogen is now joined to the carbon that was previously bonded to the boron in order to form on new CC bond. In this coupling reaction, we are maintaining the configuration off the vinyl. Hey, light as it was before the couple ing here. So in our first example, you can see we have CIS and trans I simmers are not possible for vinyl highlights as one of its SP two carbons is bonded to two identical substitutes which are ch three in our second example Now the configuration of the double bond of the vinyl Hey, light is trans and so it's configuration must be the same in the product as you concede. This is a trans confirmation and then we also have the trans in the final product. As we stated in the sentence just above all reaction

So hank reactions occur when coupling of a vine Alec or on a roll highlight was an alky in the presence of a base. So an example of a base we might use would be traced all aiming, for example. And then we also need to have a palladium catalyst present. And so in the reaction in a single bond is formed between our SP two hybridized carbon off, both off the compounds him. So with this information in mind, the following products off form using the starting materials that we are provided with. So here I've got a well, we have a double bond present, and then we also have a C triple bond and where we have 180 degree bonding angles, we've got our second structure where I've abbreviated my aromatic for Pete, a chair that means senile again. We've got a double bond and then lastly, we've got that a might functionality. Looking at our side structure here, which is labelled three again, we have an aromatic a double bond, followed by another aromatic structure where we also have an oxygen present. And then our last structure here is quite simple. Just one more benzene ring. Two double bonds that are present here. So these can be d localized and we can seek stability through that arrangement of atoms on. Lastly, we have our carbon ill.


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