5

ICHaCHaS1J31 10 or otherwise inequivalent) with different numbers diastereotopic or letters, and label H atoms that may have different chemical shifts (are SIJQUnu ...

Question

ICHaCHaS1J31 10 or otherwise inequivalent) with different numbers diastereotopic or letters, and label H atoms that may have different chemical shifts (are SIJQUnu Jlues 'HNMR pedtrum with tuc: exchangeable) in the following compound enantiotopic shift (are homotopic Cnemcat Ine Bmne that must have HOmI pts ) LabelH (10

I CHa CHa S1J31 10 or otherwise inequivalent) with different numbers diastereotopic or letters, and label H atoms that may have different chemical shifts (are SIJQUnu Jlues 'HNMR pedtrum with tuc: exchangeable) in the following compound enantiotopic shift (are homotopic Cnemcat Ine Bmne that must have HOmI pts ) LabelH (10



Answers

Compound having difference in structure due to difference in the manner of attachment of atoms are called structural isomers. They are further divided into chain, position, functional, metamers and tautomers. For example compounds having a molecular formula $\mathrm{C}_{\mathrm{n}} \mathrm{H}_{2 \mathrm{n}+2} \mathrm{O}$ can show chain, position, functional, metamerism, isomerisms. How many structural isomers of alcohols of the molecular formula $\mathrm{C}_{5} \mathrm{H}_{12} \mathrm{O}$ are possible? (a) 5 (b) 8 (c) 10 (d) 7

The I don't remember the Cuban Mhm. The chemical fits our night through Meeting di Natal. Begin and try Natural meeting. See Extreme, you know. Do see it too. I know. Dude joins and see it. I know the address. The chemical ships off the three brutal 6.113 And by your own point, I know 7.52 that's it is one. Well, the night to group is ideal from trying. So the programs are highly defeated. The more the night number of nitro groups, more day she lived, the proper will be so we can expect c h to appear at 7.2 on this is the most difficult for these three. So this will be having the least to be given. No was to begin more things on. This will be having never do 6.1 and this will correspond toe 4.33 And that will be having the highest typically

High in the given problem from the chapter a week in general kinds a molecular formula of is given. That is C. Five question. We have to write the structural formula as well as names of all the Elkins with this molecular formula. So the first structure with this molecule from LA possible is of one painting that is see it's two double bonds, C H c H two ch two, CH three. We can name this compound has won by 19. Then we can shift the position of double bond and write another structure that can exist in the form of fists and trust my Summers. That is one of the structure is this. We are the two hydrogen atoms bonded to each of the double bonded carbon atoms are on the same side of the double bond. And this Osama represents this configuration. And so we can name this compound as cysts to painting. So we can make another structure for this structure. That is the Trust I Summer were the two hydrogen atoms bonded to the double bonded carbon atoms are on the opposite side of the double bond. And the name of this compound will be trust to melting in all the in both these compounds, carbon number two has a double bond with carbon number three as shown here. Then we can write another structure with the same molecule formula that is of elkin. That is Ch two double bond C. 100 to C. H. Three. Ch two, Ch 3. And the name of this compound can be redundant as two metal one. Beauty. We can also write another structure that is CH two double one, C. H. Ch having CH three wanted to it and then CH three. And the name of this compound comes out to be three metal one beauty queen. Then we can write one more structure with this molecular formula that is CH three C, having CH 300 to it, and double bond CH CH three. Where we can name this compound on the basis of numbering and the name of this compound will be to metal to beauty. So all these structural formulas are the formulas of the Elkins, which have the molecular formula C. Five H. 10, and their names are also written with them.

We just naming on drawing structures for our Keane's that have the molecular formula C five, age 10 where we have a hidden to consider our CIS Trans. I saw more ism. So firstly, we've got simple example off Juan Pantene and then we move on to have our second example Where are double bond is simply moved to the second carbon bond in the chain. However, in our examples below, we're starting to move functional groups. So here we have a 1234 carbon chains of that beauty and where we have a missile on the side carbon three missile buttes one ain And finally we have the alternative structure off all cysts. So this is all CIS pent to Ian. So now, just to go back and make provision where we have all trends pent to mean, this just means that with our trance structure we have a six extra confirmation. What was with assists? We have a C confirmation I should conceit with the highlighted green drawing

To draw stereo ice murders of a molecule with the formula C five age 10 with a double bond. Since it's an AL Keen, we will draw, Um, a few of the molecules will be a five carbon chain with a double bond in different spots. And then we will also have some four carbon sheen's with medical groups, attach to different places and all center changing television of our double bonds. And then, after we do that, we can determine which compound will have a system trans face murder. So pressure will start with a simple far Kurban Shane Well, but the double bond between Kerman one and carbon, too. The lines were present, the hydrogen, and they will look like this. This gives us 10 hydrogen and five carbons and a double bond. Next, we will have a wide carbon chain again. Instead of putting the double bond between carbon one and two, we will put it between carbon two and three and again add, uh, lines to show these hydrogen. And again we have five carbons tonight. Virgins. Now, if we move for our next compound people to stuff a bond between carbon three and four, it will be the same as this compound here just looked around. So instead, we're going to do it for carbon chain with out of a bond between. Carmen wanted to and we'll have a metal group. Put it here and then are the hydrogen. That's one option for our four carbon sheen. Another is we can have the method group here again, but put the double bond in the middle between, um, thes two carbons and then out or hydrogen in. The last option is to have a for carbon sheen and put the metal group here and another one over there. And this gives us five carbons and and 10 hydrogen. So these are the possible story I summers of a compound with this formula, and of these ones we can determine which will have a sister and by summer's. So the answer is this 2nd 1 here. Since the carbons attached to the double bond, both of them have two different groups on each of the carbons. So this car on the left is attached to a hydrogen in the metal group, and the carbon on the right of the Taliban is attached to an ethyl group. You know the hydrogen, all of the other compounds? Um, I cannot function in trans I summers. For example, this 1st 1 here, carbon on the left of the double bond is attached to hide regions. So since those are identical, none of them have priority. And the same goes for the rest. So the only one that confirms his entrance I summers, this is second compound here.


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