5

4_ Draw the reaction coordinate diagram for the mechanism you drew in problem reaction 5_ 5. Rank the following substrates in order of...

Question

4_ Draw the reaction coordinate diagram for the mechanism you drew in problem reaction 5_ 5. Rank the following substrates in order of

4_ Draw the reaction coordinate diagram for the mechanism you drew in problem reaction 5_ 5. Rank the following substrates in order of



Answers

Draw the mechanism for the following reaction:

Hillary won. Today we're doing Chapter 23 form 60 Mistral masses to draw the stepwise mechanism for the falling reaction. So we have Is this on had a monocle here on DH? What we're doing is we're reacting with strong base. So after reaction of that strong base, what's gonna happen is that we're in a deep roomie, one of the protons using this option and I own and deep resonates this Alfa Croton making by your makeup on You're breaking bon and those two electrons and that signal bomb, they're going to go into that oxygen nucleus that on that carbon nucleus. So now you have and I only Corban on, which is very nuclear feel like and very reactive. So it's going too easily react with this election file that you add on one of these carbons making about your makeup on your break, a bond and the bonds in the break. No, What you have is one to carbon and another Fox and Anna are on, and I was auction. Ion can actually react with one of these electoral Filic Carbonell carbon centers to form an intra molecular cycle ization reaction in which you form a new signal bond making bonds. You break this, Cardinal Bond, This criminal bungle collapse back down And they needed kick off your leaving room being this death oxide. So then what you have is now the cyclical structure here with your cardinal here in office. Carbon all your ethanol. So long or actually, it's eat your minus. And that's where this acid comes in Because it was going pro, Nate. Everything and make everything neutralized to form your final product with ethanol.

With With him we live in I dried. First thing that Volker is thie nuclear Filic edition of this hydride source Both Then produce This is Tetra. He'd ral intermediate. He with him will be the counter ion to the oxide Then this chloride get kicked off she'll have to be with you Counter Ion It's now if produced and Alba hide that's all. The hide is very reactive. It will still react with another equivalence of with him Aluminum hydride Now, once we formed this tetra he'd roll into media will notice that there are no good leaving groups. So the Alcock side is going to stay as the species until we get Teo Step two, which is the crunching of this reaction. It's water, Of course. Now this step Harlock oxide can get pretty nated. You'll lose with young hydroxide and produce ethanol

What you understand the mechanism. This reaction. Let's examine the reaction first. The substrate is a tertiary Allied. Yeah, and the products consist of a substitution product put in an elimination product. Does your inner light can undergo substitution or elimination under my basic condition? No, either Off this product for mission involves a car, bucket and intermediate, which can be formed by the removal ofthe reminded post. Really, the Suri car look attend forms, and this car, like a ten, either takes Electron from the nuclear file to give a substitution product court. It can lose a bitter proton look at the elimination product.

Now the question is dry. Stepwise mechanism for the following dish step was mechanism for the full English. So industry a shine. Here it is, actually intra molecular new beautifully substitution off. Hello, Jin, which is taking place on by Jack, please. Product is formed and the mechanism of the reaction will be quite different. Chrome s and Bernard isn't true. The product for mission can be explained by different mechanism. That is addition Al ignition mechanism. Because nuclear Felix substitution direction is not that common in bands ending normally. Electro Felix Constitution is still in place, so here the mechanism will be initial elimination election. Let us see how it is sticking this. So first off for here the product and he dumped molecule is one been changing one hell virgin here. And let's stop the part of the molecule. We have to bend in such a way. So, Dave, we can get the part of dizzy night. Prison should be here with the hydro son and me take having going on. So this is the new clarify which is goingto intervention. So how did you shake is sticking, Please. First tape first jet skis. Step one. That is addition off new blue file Nuclear fighting D'oh! Get the got a bull And I am so edition is taking place here and discover Enitem where the clothing is a dist and and I am is from to you So But it is the product which is formed is no thinking two t you did she clueing. And night drizzle is going to adopt you with dyed Rosen Team group Make this. I ain't negative. Charge Pierce here and double gaunt after Ben's thinking, will you sing? And here night reason is giving a trampy l suppose it'd charge abuse Absolutely. In the next jet, this carbon and I am can be stablized by listening structure. So nest isn't everything still just should be. This negative charge is for me the long here and this bar will be no more here. And it is from the charge of him. And by this the structure from the ease bench in dream Negative charge here doesn't Bond is here. Cloning will be here and this whole group is It is too. Benji Nitrous Is that this year velocity charge or the mattress in I'd risen is Janet Jackson and take so this meeting in here. And this is the negative charge on this is the double on just formed by the shifting of Detroit. So they shoot you The second resident in such a in the Tardis looking structure. What this negative charges from you boned in between these two. Cut on it. Um, and this devil born will be no one here and form the judge. So the next time to shoot me negative charges that beating here during one is here. This stomach one is here, and clothing must be here and the whole art He's going to a ditch here with the positive charge of electricity. We take her with him in here, and I So this is the third reason that instill Children because of this incident. Instructors at Jenny this, uh, garden and and he's stepping. And after that, this is reality Charge is forming the bond. Second step is studying this negative charges from the bonding between these two carbon in Tum Onda. Breaking off the clothing is taking this. So clothing is taking the trunk here and going from the molecule a seeing minus and after dent, the garnet brooch is formed. These this is the next step product. Ese wrenching ing. I don't want you here. And the stolen one is formed in After that. Cloning is no more here and name Johnson Week. This horn quote is here with the metal group was a charge. Oh, in the next Jim, it is losing and the kind of God it is hoped. Giving your CIA turn two natures and and other funny product is fault. So this is actually a Step two May elimination of halogen misty oh, engine that screwing this taking place. And by that, I wanted in the product so that it's like this one, but in his own Islamist initial initial mechanism and the final product is the quiet part forms. So that pistol when thinking, mate, this whole intra molecular reaction on it, the distant chosen I mean, just a distant thinking. My new clothes, Felix institution and mental so distant credit for yeah,


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