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1,) Pleuse nune the following compounds;2) Pleuse druw the products of these reuctionsH,) What ure Ihe praduets oftl: reuctions helow (hint; elimninution)?HSO...

Question

1,) Pleuse nune the following compounds;2) Pleuse druw the products of these reuctionsH,) What ure Ihe praduets oftl: reuctions helow (hint; elimninution)?HSO

1,) Pleuse nune the following compounds; 2) Pleuse druw the products of these reuctions H,) What ure Ihe praduets oftl: reuctions helow (hint; elimninution)? HSO



Answers

Give the products obtained from mixed aldol additions of the following compounds:

Yes, Arrest to draw the products, the following Aldo reactions. And in the first one, we have a for carbon chain reacting with a five carbon chain and this is reacting with. So if you reacted with a strong base like sodium dioxide, it's gonna deep learning at the alpha hydrogen. So these are the Hodgins, located on the carbon adjacent to the carbon carbon. So you can either take this one or this one. Obviously, I have to take this one, but obviously we can get some products. They're reacting with carbon iron here, grafting with structure. So it's going to attack the carbonate carbon because it's very electric milk because the oxygen draws electron density with the carbon, and it's gonna be one two. So whatever attacks is going to be the next number. Just three, 456 So carbon one was the out ahead two is was a carbon on and three. So this is over water to give us an alcohol. Three is not alcohol. Yeah, and on carbon three, we also have this purple around carbon to we have this purple satun. So if we react this with either base and heat or H three a plus and heat we're going to get and are keen and get rid of the alcohol. So have a dehydration reaction. You can get that. But this is going to be products and the dehydration products. I guess it would be we have permanent reacting with three pennants. Yeah, let's use 13 hydroxide, So I'm gonna have it grabbing. It's hydrogen from the structure. This is over water. Give us an alcohol. So it's going to attack the carbon carbon, and we're going to get So this is one, two, 345 I'm sorry. You should, um all right. So this carbon right here, it's gonna be one. This is two. This is three, four, five and six is your key tune, And we're going to get carbon. Tuesday cartoon through three was the carbon Iron four is now an alcohol, and carbon four is also attached to this Ethel saw janitor. So we have stage two ch three, and I think it's a Okay, So first, see, we have, um, cycle Jackson reacting with per panel or yeah, criminal. Okay. So, sodium, with oxides going to pertain. Eight, this ha jin are here, so we'll get a carbon ion and then reacting with personal. And this is it with water, too. Just one Tuesday, carbon iron, one person gets removed. Then 345 to 12345 345 the alcohol And three. And that's it. Okay. All right. So for for D, we're reacting formaldehyde with group in Oregon, so it can only pertinent one structure because from alcohol doesn't have any alpha hydrogen. Ah, water. So it's gonna take this one, and we're gonna get a car. Bet on. It's reacting with formaldehyde. We're going to get a 212 three. We have a primary alcohol and on carbon to even metal. Do this This method order. So free. React this with formaldehyde again and obviously going to urinate the other Ha jin Right here. Okay, this should hold on. This should be Let me make sure I was right. So you have 123 And then 123 So it's gonna person eight. Um, this hydrogen and we're gonna get a carbon iron to attack from Al Jihad. So drawing structure again. Okay, so we have if 123 So we can we have a three carbon chain. The primary alcohol, carbon ones, the formaldehyde, the AL to hide and then on carbon To We have the methods, though, but we also have the addition of this siege. 30 h group. See right there, stage three and then you can't react this again because we're out of alpha hydrogen. That's the answer.

Okay stressed by the products in the following next all the edition and in the first one we're starting with a four carbon Alligood and some drafting with a five Carbon and a Hood. So treating this with a strong base like starting with oxide is gonna department the alpha hydrogen on either of these structures. It's a deep trinity here. This is going to attack the outer heard and with the water. Get the alcohol. So this is 12 3, 4, 5 and six. and drawing the outer hide on the structure. 1st 2 3456. Carbon three is now on alcohol and carbon to is attached to this purple tuner here. And if we treat this with acid and heat or basin heat, we're going to the alfa beta Erdogan Naquin. Get this Mhm. So for B we have a three carbon Q tune, reacting with a five barbecue tune. So it's super afternoon with three pennants and again with sodium. I'm gonna use sodium dioxide this time, it's gonna department the alpha hydrogen on one of these structures and checking the carbon carbon accounting for the Q two and we have 12 34 So 1, 2, 3, 4 and carbon to is attached to this method right here, This is carbon 2, 1, 2, 34 Carbon three is gonna be the he's gonna turn into alcohol and carbon 30 is also attached to a metal this method right here, so I get that and obviously treated with the same thing and be, I mean in a either acid heat or basin, he will give us an alpha beta unsaturated ketone. The first, see we have Cyclo Hexane in with a three carbon at a hood. You assume with oxide. Again, it's gonna deeper anything alpha hydrogen on either of these structures. So obviously one could attack two if one's deep originated or in this case Tuesday impersonated. So it's gonna attack one so we can get a mixture products. This is going to attack the cardinal carbon and we're going to draw the auto had first so 12 to attach to the method right here and three is going to be the actually no, let me draw this way. I'm gonna have, I'm gonna deport me the alpha hydrogen on cycle accident. This is going to attack the carbonell carbon because this carbon is more accessible because you get hydrogen here so you get a better yield of this product. So drawing cycle accident first and so it's gonna be 1234 and five 12345 two 345 carbons Case of Carbon three. It's gonna be alcohol and it's also attached to And that's that's it. And yeah, should be it think. Yeah, okay. And I for a day we have excess from AutoCAd with Peru panel, So we only have two Alpha Hodgins And drawing the out ahead 1st on two three. This will be a primary alcohol and carbon to is attached to the method order. That's a product.

Okay, so rescue the products for foreign reactions. And this is an acid catalyzed dehydration. So we're using an asset as the catalyst and dehydrated dehydration means while the loss of water are the loss of away from the structure. And um the first one is cyclo panel, so with the acid a strong acid like sulfuric acid heat to promote dehydration. The first step is 40 H. Departing the acid and turn itself into a better leaving group. And the college get base of sulfuric acid is going to which will be S four minus. It's gonna grab parts on from the Jason carbon for mannequin and expel O. H. Two plus which is water. And it's going to do this anarchy. So it's gonna grow apart on leading to the most stable a keen X one is. Um we have a seat of error. The structure to a benzene room attached to a two carbon side june and again it's gonna create Naquin. So there's no puritans right here because we would have too many bonds we already have on here too. Three. And obviously this one. So, so there's only parts on on this carbon. It's gonna lead to not keen right here. If we just had cycle vaccine, then it would form, yeah, keane right there. But we don't hide regions. So she put H plus for some acid with heat and then see is um the structure oops to have the same situation here. It's going to grab this person and it can only put the key in right here. You can't put it here because we have too many bonds. As a result, we're gonna get the structure. So for the first one, if we had a methyl group right there, um it would grab a person from the adjacent carbon and put the Aqim right there because we have an extra our group in the metal. But obviously we don't have in the actual example, we don't really have any are groups so it can guard birds on from any carbon, but it has to be the carbon adjacent to the labour group. It can't be like this one or this one.

Okay. So here we have not the meth oxy. So if we treat it with chlorine gas, you will get the coronation as the usual Ortho para position. But since the pere position is blocked. Okay. That will cause us to favor the Ortho wake or it will direct sports Ortho since Ortho now is the only possible direction. So most likely this title here, it's more favorable against this site but the other substitution as possible as well. Okay next we have room have to leave and if we treated with a chlorine gas as well. No um rural mean intelligence are Ortho para directors that even though they are d activators. So it will be the same on a now the molecule. Okay so here we'll get you know college nation of the parasites probably over the are so psyched. Can't now we have a muscle napster. So methyl groups are also Ortho pair directors. Okay. And the parasite. Okay. And I'm seeing the peril position. We'll get the origination preferentially. Lastly we have a nature napfa Susan. This is at the yacht waiting group, uh, deactivates the whole entire rink, but it's attached to does, allowing for a substitution now on the other inc here, the opposite position here. Okay. And there we have it.


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