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Indicate the following products, reactants and/or conditions that would be required to carry out each of the following synthesis (the Znd synthesis does not require...

Question

Indicate the following products, reactants and/or conditions that would be required to carry out each of the following synthesis (the Znd synthesis does not require MCPBA)HO

Indicate the following products, reactants and/or conditions that would be required to carry out each of the following synthesis (the Znd synthesis does not require MCPBA) HO



Answers

What reagents are required to carry out the following synthesis?

Okay, This problem is asking us to synthesize thes products from my starting materials. So let's go ahead and start with the very 1st 1 So this very 1st 1 I recognize that I have a broken here. And then I formed an l came here. So the thing about that all keen is it's not particularly substituted, right. We only have to Hodgins associated with this carbon on the O'Kane. And then we have this carbon associated with this carbon on the key. So it's only a mono substitute, okay. And generally, with the formation of Hawking's in elimination or actions, I form the most substitute. Okey. So when I formed right here is not a very subsidy scheme. And we know that because my bro minutes attached to this carbon get If we're direct this with sodium hydroxide, for example of most likely forming cocaine right here, that would be a dice up signal came that would be the major product. So when you want to form a at least have a reaction that incorporate this model subsidy scheme and generate, that is as a favorable reaction. So also, judging by the fact that the last couple pages in the textbook at the last couple problems have been dealing with health and eliminations. I'm gonna do exactly that. I'm gonna wreck this compound with extra connected to 123 method groups fit. And by doing that, this next Gen will perform a substitution reaction. It will go ahead and attack that carbon, replacing that bro me. OK, it's just a substitution reaction. So what that does is it forms this ch three safe to ch two. And instead of that broken cakes to my carbon, I now have next gin with 123 method groups with a positive charge of nitrogen kit. And then, of course, I have the remainder of my compound street. Okay, so now I'm at my Hoffman inflammation point because I can just react this compound with silver oxide in water and that's going toe form a high drops that I am to be, ironically bonded with this compound right here. So let's go ahead and act out with silver Roc side A G 20 and water. That's conformed, they say. Was that compound the only difference being that my hydroxide is now ironically bonded to it? Okay, so let's go ahead. And to put that and then one would do is at a hydroxide ion right here. Okay, now I'll have to do is utilize heat. He is going to facilitate the Hoffman elimination reaction in which I d protein ate the carbon with the most Hodgins in the beta position. So this election right now, we can consider that Adam number zero. And then, um, here we have Alfa carbons, which are one away from that and then one away from that awful carbon right here and right here are my beta Karpin's. So this hydroxide is gonna go ahead and deep pregnant the carbon with the most number of hydrogen, which is this one and that will form my product. Okay, what about this one? So this one, Same exact thing. We recognize that we have a natural compound and we have this basically stretched out carbon train. Right now, that carbon chain is in the formation of a rain. We want to stretch it out in order to form that linear structure. So what I've been doing is recognized that I already have my 1234 carbons. And in my product, I also have 1234 apartments. So what I need to do is get rid of this nitrogen hoops is get rid of this nitrogen and in the process makes him double bonds. Okay, so what I'm gonna do is react this with C h three I in excess. Okay. And I'm gonna do that in basic conditions. It's OK to see or three. Okay, that will form it. This product, that should be a four carbon compound. Okay. And then I just had to methyl groups to it with a positive charge. Okay, so the purpose of doing that is to for my ammonium, so that can proceed with Hoffman elimination. Okay, so what I'm gonna do now is reacted with a g 20 and water, and I'll just do this on state. Same step with heat, and that's gonna form this. It's gonna go ahead. And deep protein ate my beta carbon, which is this one. So take off the hadron, move the electrons onto this bond and move the electrons onto that nitrogen to form in this compound where I have my O Keane here. The remainder my compound. So should be like should be over here. I'll just reach all this. So there's my talking. Here's my compound. And then the connection to my next year with 12 methyl groups. Okay, Right now, this what I just right here is not the same as this. I still need to get rid of that extra, because I still need a double about here. I still need to get rid of this nitrogen. So what I'm gonna do is same exact thing that I did before. I'm gonna racket with ch three I in excess, or just see FBI in general to make another method group there to have a positive charge. And then we can proceed with another Hoffman elimination. So that could take off you 100 on that to make an O Keane there. Right? So what I'm gonna do is ch three. I that's gonna add a methyl group to see history. I So I have now is the same thing just with an extra method group. So that means that I have a positive charge on the nitrogen and then using a G to wealth. So we're oxide in water with heat. I'm gonna go ahead and take off this 100 moving the electrons onto here and then moving on the electrons on that I just didn't as a leaving group, and then I should form my product, okay?

So continuing on with our work with Aldo hides in key tones. So what we have in the common functional group is C o What changes is through our groups which can be protons, hydrogen or other carbons where we have to to all groups we have I liked your Philip Carbon. We also have our oxygen atom which has a partial negative charge associated with it. So jumping straight into this reaction we have PCC is are highly selective re agent on. We can use insolvent such a ch two c l two so we can oxidize the primary and secondary alcohols to generate carbon al compounds to for example, we have here Hey, Joe pcc c H two see how to we then generate the following. I'll do hide So the reaction of alcohol hides with lethal magnesium bromide gives on alcohol a swell. So in this reaction, we'll use the material that we had just before in the presence off ch three c h two MGB are e t 20 followed by NH four Seattle Andi water each tour. We don't generate the following So now we have an alcohol instead off and all the hide So then PCC can oxidize the primary and secondary alcohols to our Carbonell compounds. So again we take the above material PCC presence of ch two c l two on What we generate is the following final step. We have the key. Turner's reacted with a grin yard re agent which allows us to add on our hydrocarbon chain that is missing here on we can transform our ketone into our alcohol group in the final step using the following re agents MGB all that is our green Yard re agent in the e t 20 solvent, then followed by and h l C L on h 20 is our final step NH four c l and H 20 allows us to carry out that final chemical transformation. Nothing has changed. Our cyclo hexane or that we have altered is our substitue INTs. And now instead, off that Keith and we haven't o h group, followed by two hydrocarbon chains to generate our final product

So continuing on with our work with Aldo hides in key tones. So what we have in the common functional group is C o What changes is through our groups which can be protons, hydrogen or other carbons where we have to to all groups we have I liked your Philip Carbon. We also have our oxygen atom which has a partial negative charge associated with it. So jumping straight into this reaction we have PCC is are highly selective re agent on. We can use insolvent such a ch two c l two so we can oxidize the primary and secondary alcohols to generate carbon al compounds to for example, we have here Hey, Joe pcc c H two see how to we then generate the following. I'll do hide So the reaction of alcohol hides with lethal magnesium bromide gives on alcohol a swell. So in this reaction, we'll use the material that we had just before in the presence off ch three c h two MGB are e t 20 followed by NH four Seattle Andi water each tour. We don't generate the following So now we have an alcohol instead off and all the hide So then PCC can oxidize the primary and secondary alcohols to our Carbonell compounds. So again we take the above material PCC presence of ch two c l two on What we generate is the following final step. We have the key. Turner's reacted with a grin yard re agent which allows us to add on our hydrocarbon chain that is missing here on we can transform our ketone into our alcohol group in the final step using the following re agents MGB all that is our green Yard re agent in the e t 20 solvent, then followed by and h l C L on h 20 is our final step NH four c l and H 20 allows us to carry out that final chemical transformation. Nothing has changed. Our cyclo hexane or that we have altered is our substitue INTs. And now instead, off that Keith and we haven't o h group, followed by two hydrocarbon chains to generate our final product

In this problem, we have to convert to alcohol's first one. See, it's thing. See, it's true. Three extra for it. Oh yeah, One proposal. So see it stayed. See it We are See extra via Thank you, girl. So to growing items can be other. He took albums by In addition, you know that everyone to come home. So if you take responding no longer yeah, it's double want here too. Oh, cool. It is not roaming two propane deals with a group of cocoa. This can be a pink by the higher education of alcohol off preneurs. Using unethical list like satirical, it's toe my message toe. This therefore people the second more interest conversion a few two weeks by works C two, h five or H is converted into C H three. See everyone Oh, c two or C to its way Now pills are made from alcohols and corresponding attics so we can can work. You can get this with a monograph situated by way. Mhm. Uh huh. Pacific gas it see it's three he boy in presence of an Africa trees when you disaster on its own, or can be more your personal that you convert and doing more off. That's if you guys it. What operations with, uh, it's 204 or production diplomat and severely Catholic will also raise this. Do a pretty good on that can be reacted with, uh, either alcohol in business of monastic that leads from the required.


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