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What is tho relationship OH betwoon the 3 1 compoundsthey they are they are identical #ey arecoastortora are Meso diastereomers somersOHOH HC...

Question

What is tho relationship OH betwoon the 3 1 compoundsthey they are they are identical #ey arecoastortora are Meso diastereomers somersOHOH HC

What is tho relationship OH betwoon the 3 1 compounds they they are they are identical #ey arecoastortora are Meso diastereomers somers OH OH HC



Answers

The relationship between (a) they are enantiomers (b) they are anomers (c) they are meso compounds (d) they are diasteromers

Let's identify the relationship between molecules and each of the following peers. For a the two molecules are identical for be two molecules are a constitutional I summers for C. There is no relationship for D. Your constitutional is MERS. And for E, they are Steri oysters.

Let's talk a little bit about ice, summers and relationships between molecules. So there are two different types of higher classifications of ice summers. So the first type of classification of ice summers are constitutional ice tumors. Now constitutionalism er's are molecules with the same formula, but different structures. Our second type of ice summer is a stereo is, um er. Now a stereo is, um ER is part of a larger subgroup of ice MERS in which a molecule has the same formula and the same type of structure, but a different configuration or a different confirmation. So let's go ahead and look at some different structures and determine what type of ice MERS they are or if there's no relationship between the molecules. So our first structure. Here we have C H three see, which is double bonded to an oxygen, as well as a hydroxyl group, our second molecule. Here we have CH three bonded to a carbon, which is bonded to hydroxyl group as well as double wanted to and oxygen. So let's take a moment and look at these molecules here. If I were to flip this molecule around, which means we'd have a double bonded oxygen with a carbon and then a ch three and an O. H and then rotate this molecule counterclockwise. We would have the same molecule. So therefore this first one is the same for a second example. Here we have a ring. We have a five sided ring with a hydroxyl group and a double bomb. And then we have a five sided ring with a oxygen double bonded to it. So obviously these molecules are not the same, which means that we either have no relation. Constitutionalism, er's or stereo is a MERS. So in terms of determining they're types of ice MERS, let's determine their formulas here. So we know we have C s. We have HSM you owes. You're sees with ages and their past. So this has 12345 carbons. This has 12345 card. This one will have 2456 78 hydrogen zones. This one will have 246 eight hydrogen, one oxygen and one oxygen. They both have the same chemical formula. Okay, so then they must be either constitutionalism, er's or stereo. I summers. Now the definition of a constitutionalism er is a misnomer that has the same formula but a vastly different structure. Therefore, these air constitutional I summers okay for our third structure. Here we have another five cited ring, but we're going to start to get a little bit tricky here. So on our five sided ring, I'm going to redraw that because that does not look great. Okay, on our five sided ring, we have some directionality within our methyl groups. Here we have a methyl group coming out of us and a method group being sent to the back of the page. Whereas on this second one, we have a method group going into the page on a method group coming out of the page. Now, this requires some directionality thinking here, if we were to flip this molecule so I'm going to use this curly shape to say flip, would these two molecules be the same? So imagine a carbon coming out at you if you hold your hand facing your face and you were to flip your hand over. Is it the same? No, You're looking at your palm and then now you're looking at the back of your hand. If you were to stick a finger out to represent the seat, the methyl group, and then flip it out. You have a method group facing you, and then now Method Group is a way. Therefore, these are called stereo stereo ice summers for our fourth group. We have a huge aromatic molecule here that I'm going to go ahead and draw some Mexicans for. If you're hexagons, look kind of funky now, don't worry. After many years of organic chemistry, you will become a hexagon pro. I promise. Okay, so we have a double bond double bond, double bond, double bond, double monitored oxygen, oxygen. We have double bond, double bond, double one, double bond, double 12 and oxygen double wanted to an oxygen. So visually, these look like constitutionalism. Er's. However we always it's good practice to double. Check to make sure that these molecules are actually the same. So one carbon. 23456789 10. 123456789 10 Carbons. 123456789 10 Carbons, hydrogen. Okay, one hydrogen, two hydrogen, three hydrogen four, five, six, 78 nine. Hydrogen into oxygen's Here we have one. I was just kidding. It's gonna be eight. Sorry about that. Actually. Every count. 12345678 Yeah. 123 for no, no hydrogen here. Five, six, seven, 123456 six. When I was wrong here again, there's gonna be no hydrogen in these corners. Well, I'm not even looking at my notes. And you need to look at my notes when I do this six and then two. So these are, in fact, constitutional ice MERS. Okay, last structure. We have a four sided ring shaped kind of like a rhombus. And always remember, when you see rings that are less than five sides are you are getting significantly more strain on these bombs here. So if you think about this as the number of sides decreases, strain definitely increases. However, is the number of side increases the stability. We'll also decrease because if you have like a 45 sided ring, it's more likely to break. So look for that six sided sweet spot. But rings can really be any side if you have the right Kyra Ality as well as the right monastery. Okay? Besides the point. So we have a facing up roaming and facing down, bro. Mean and then we haven't up down broking. These molecules are the same, but they're shaped differently. Therefore, we're gonna have constitutional ice allies.

Starting with compounds, eh? So the easiest way to go about this problem is to try and rotate these three groups. If you change just where their positions are around the carbon hydrogen bond to match the other compound, then you can figure out their relationship. So if we're moving around this carbon hydrogen bond, we can take this siege to H move it to where? The bro meanness that pushes the bro Ming up top and the methyl group down to where this siege to a wage wass. And when you do that rotation around that access, you get the same compound. So these air identical. If you struggle to see this, I would buy or borrow a model kit to help you visualize it. Play with it until you can actually see the rotation around that bond within your head. For part B, um, it looks like potentially these two could be the same compound. They are actually an anti merce. However, because the foreign groups that are attached you cannot draw a plane of symmetry through this point. So it's not me, Zo. It is actually in an anti works. You flip this stereo center that's on ly make it a double bunk or all of them for a change

Yeah, we have given question is examine the relation between the following pairs of compounds. So here we have option A, B, C and D. Here we have given option C is direct option. We have one structure. One structure to structure to our I didn't tickle and stick to three is is normal eyes open. So here ISA Mark molecule having customers having same molecular formula, but different structure formula SAM molecular formula, but different structural formula. So here identical as me. They have street Children into. Yeah, they have same configuration, same configuration. So here we have option CST production.


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