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Chzuz suzui8 HvvDraw all the significant resonance structures for the compound below. A complete answer will include all the curvy arrows required t0 generate each ...

Question

Chzuz suzui8 HvvDraw all the significant resonance structures for the compound below. A complete answer will include all the curvy arrows required t0 generate each structure from the one before it;Provide a bond line drawing all of the products for the following reactions. When appropriate indicate the major product: Make sure to include stereochemistry where appropriateSnl /E1 NaSH- HzO (solvz |NaSH THF (solv:)MourSn2HoflmanCH;CN (solv:)Provide a bond line drawing of the major product(s) and a

chzuz suzui8 Hvv Draw all the significant resonance structures for the compound below. A complete answer will include all the curvy arrows required t0 generate each structure from the one before it; Provide a bond line drawing all of the products for the following reactions. When appropriate indicate the major product: Make sure to include stereochemistry where appropriate Snl /E1 NaSH- HzO (solv z | NaSH THF (solv:) Mour Sn2 Hoflman CH;CN (solv:) Provide a bond line drawing of the major product(s) and a drawing of the mechanis for the following reactions A complete answer will include all the curvy arrows coccan forthe followina reaction Methanol (MeOH) is only a solvent in the



Answers

Draw the product by following the curved arrows. This reaction is an example of a [3,3] sigmatropic rearrangement, as we will learn in Chapter 27.
a. What carbon radical is formed by homolysis of the C- H$_a$ bond in propylbenzene? Draw all
reasonable resonance structures for this radical.
b. What carbon radical is formed by homolysis of the C- H$_b$ bond in propylbenzene? Draw all
reasonable resonance structures for this radical.
c. The bond dissociation energy of one of the C- H bonds is considerably less than the bond
dissociation energy of the other. Which C- H bond is weaker? Offer an explanation.

High end this problem from the chapter and Kings and Sultans were given somewhat incomplete addition reactions. Well, keen, we have to draw the structural formula for the product in each of these given reactions. So the first reaction is that's where we have the molecule protein reacting with hydrogen roommate. So in this reaction the double bond of the propane is converted into the single bond and hydrogen and Romania added to the double bonded carbon atoms. And the product form in this reaction is CH three, CHCH three with blooming bonded to this carbon atom of the center. The name of this compound can be written is to remove propane. This is an additional reaction whereby a molecule is added to double bonded carbon atoms of the elkin to form the subsidy to the team. Then we have this molecule which is A cycle. Oelke cycle came having the CH two group bonded to it by double bond and HBR is added to this molecule. Again, the double bond of the molecule is converted into the single bond, and the product will have all the carbon carbon single bunch. That is a product will be saturated compound. We are, we have CH three and bro mean bonded to the ring. The name of this compound can be written as one normal one metal psychlo hugs in. So these are the products obtained by the reaction of Elkins, with which we are, as given here.

Okay, so I want to give the akin produce in the following reactions. And the first one is we have ethanol. So it's two carbon alcohol. And again this is reacting with a strong acid and he so it's going to grab it on from the acid. And the county based Sina grab hydrogen from the structure and former Naquin expand labour group which will be water. So we're gonna get ethylene and also water as side products. And that for B we have 123 so carbon to has a muscle group. And um so the first I would be the same. We'll get O. H. Two as leaving group. But um so if we draw the intermediate of the reaction, we'll have positive charger here once water leaves and a positive primary carbon pattern is very unstable. So it's going to undergo. It's called a metal shift where the method is gonna go with the card account owners and the metal. I mean the copy cat, I will go where the method is. So we're going to get a metal shift and we'll now have a secondary carbon cat on which is more stable. And here's the method group that was on carbon to so now the structure and um it's going to form this this product it grabs for its on from here and forms the Akina right there, we can insert a coin and this is more stable base with more are groups. We have this one and this one as opposed to a primary carp cattle, where we only have this one and then for C we have a cyclo external, so a cyclic structure vaccine is six and um we'll get a secondary carb account on, so we'll get the structure and um so the formula for for A is going to be CH two, Ch two, and for B. We have stage three ch ch speech to. And I think it's a.

High in the given problem. From the chapter alcohols. It hasn't tiles, we are given the two alcohols. We have to write the structural formula for the Elkins that are obtained by the acid catalyzed dehydration of these given and co host. And also we have to predict the elkin that will be the major product. So for this we will write the reaction here. The first reaction is to Mitchell to beauty in all That is CH three, C ch two, ch three and to the second carbon atoms are metal group is bonded as well as hydroxy group that is alcoholic group responded Now when this reactant is subjected to dehydration in the presence of mineral acid like sulfuric acid as a catalyst. The product form is an elk in which is formed by the laws of water from this reactant. Now, since always group has wanted to carbon number two, so Which part will be lost from this carbon and the acts will be lost from either carbon one and carbon three. So There will be a mixture of product. The first product is CH three, see having CH three double one, Ch CH three. And then there will be another product, CH two double one C. Having CH three, Ch two, Ch 3 plus it too. Now out of these two given products, this product will be the major product where the double bonded carbon atoms have more number of al Qaeda groups and this will be the minor product. Then we have the Next reactant that is one metal cyclo sentinels. Yeah this reactant is shown here that is one metal cyclo painting all here when this molecule is subjected to acid catalyzed dehydration in the presence of sulfuric asset. There will be a mixture of products formed and each of the product present. Elkin, one of the Elkin is formed, has the structure as shown here where the double bond is present in the ring. That is, I click, rain and metal roof is present here, and the other product involves the formation of a double bond between the ring and CH, two groups from where the hydrogen is lost. That is, the product is like this plus eight to now. This product formed is the major product made a real team and this is the product funded minor amount oh!


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