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VII. Indicate if the rte of the following reaction will increase decrease or remain unaffected in each of the following instances: points) CH;ONa CSSC CH; Heal The ...

Question

VII. Indicate if the rte of the following reaction will increase decrease or remain unaffected in each of the following instances: points) CH;ONa CSSC CH; Heal The leaving group is changed from Br" to The solvent cnange ed from CH;S(OJCHz to CHCH CHzCH CHzCH} The concentration of CHONa is increased but that of the substrate uncnanged The substrate changed to

VII. Indicate if the rte of the following reaction will increase decrease or remain unaffected in each of the following instances: points) CH;ONa CSSC CH; Heal The leaving group is changed from Br" to The solvent cnange ed from CH;S(OJCHz to CHCH CHzCH CHzCH} The concentration of CHONa is increased but that of the substrate uncnanged The substrate changed to



Answers

Which of the following changes will increase the rate of elimination reaction in the following reaction?

So here we're looking at 16. Mm. C'mon, I'll keel over here and let's consider it if it's PK or to be eight or 10, and that would affect not the passes. Okay, so we know. Let's say if you first look at eight p. K and A, that would mean that we would get this for me. There would be a 50% distribution of both the thigh all and violate form. And the PKK and the pH are both equivalent be a 50 50. Okay. And then if we were to increase the pH. Put this in a more basic solution than we would favour this form, and this one would not be as much. Yeah. So inconvenient analysis. We require the nuclear Filic version of assisting. You need the filing Iron ion. So, um, because we need the failure. And I are we needed to be more nucleus to look more basic. Right? So if you were to have an increase, the p a. Up to 10, technically, in a environment in an isolated environment, that increase in PK would make this more basic. You know, like the lower the PKK more acidic, higher. The key, The more basic. So this would mean more basic in an isolated system, Jim. So since we're concerning this as a 16 refugee within an enzyme like and then the active site, you went many to assume that the enzyme we're in like a binding pocket we're in a very, maybe a hydrophobic region where the system has to do is literally enclosed with its substrate with the desire substrate. And there's no there aren't any protons, you know, forming around and where this increasing BK will just be an isolated system to directly increase the basis city and this nuclear Felicity of this style. But real estate me, the pH, the physiological, the physiological pH you know of our bodies is 7.4. So then that's quite you know, it's a bit lower. So then even at a different 0.4 if you just didn't point for if RBK was still eight, we would favour the file for him. All right, But so then, if we were to increase the PK up to 10 again, I would favored the file form all the more okay at this peak, and then the only way that this would then be able to increase that this increase in PK would be able to increase. You know, the reaction rates because you have more file eat with B. In this case, where the enzyme binding pocket is just an extremely in close system about, you know, is allowing, let's say, is in a P K in a P H. That is a bit higher. So I'll just wait out there. The enzyme must the enzyme active sites must be enclosed and this isolated system and have and that, like that minute that, um just that environment that and close system is have pH that is larger or equal to 10 in that small and that small section of the environment just due to the recipes starting it. If we're able to get the pH to be greater than 10, then we would have a lot of violate present, and this increased, you know, necessity would be able to increase the reaction rate

So in this problem here, given with this great equation and we have to find our for a some changes. How about the end of the night creep oxide? And they could've Graham will change. So the 1st 1 is if we in Quinn's the consecration off the company. No, wait there. The tree outside and they revere is the prettiest. I would not change. So we increase the concentration ofthe moon. That means you're praising the concentration of and that means police the rate of the A forward direction. And that means the village off my creek oxide and thank you, Really? Really increase. Then a 2nd 1 here has to find out it became the concentration off what are? But it happens for the key off that looks like that. So if we change the concentration off water that is near imprison their concentrations off a perfect defense, some of the nitric oxide defensed that reversed its greatly increased. And that means some of the nitric oxide constant. That means that games the necklace looks like Chris. They are see when you could fight no free, decrease their constitution off oxygen. But it happened so freaking prince, their concentration of oxygen. And that means from of some of the coders that 90 bucks there and work will react the probabilities of some born again cool when you realize the change and strong and mean 90 bucks a week party. Kristoff What did happen? So if we created that's funny off the container, that was the reinsurance are they could have been the singles in your area. It's their number. Monica was present. So if we look at the reaction balance, depression, see that Realtor said four plus five brutal Monica LS the the food Except for past police took up in Monaco. So we have less than a off one concert, every inside that mystery for crystal. No, the reaction cooling their jurisdiction. And that means off some of the 19 bucks I'd react with family like that could produce from Bologna. That is, in this case also, that doesn't look like that. They quick that part's easy. Your possible find out if we add a catalyst whether or not going change. That was 96. So when you and I can tell you used whatever they resist, they're reaching grade in four directions, so off the role of the cattle is still reach in that area at a faster rate. And in that Hughes won't that forward. And then that would range from great increase, but means adding, a catalyst will not increase. Thank you. God say so. The asset question. You, um thank you. Changed for that. Looks like getting this case. And the last one there asked if the temperance share what happened. So from the delange filter, we can see that this is an egg sucker reaction. That means it is careers in this question sold freaking. When's the big furniture? That river that reverse, not the forward hatch. So because the temperature pervert the backward ancient indefinite some of the nights of Sorry, son. What? I could use some. I want you and answer him. But in this case, like you except me, Chris

So for the first part, be dealing with helium gas onda. A decrease in temperature decrease in temperature would result in a decrease in the kinetic energy off my gases, molecules and solution. Andi a decrease basically, um, the kinetic energy will result in an increase in the inter molecular forces holding the gases particles. With the actress solution, increase in intimately forces will result in an increase in Saudi ability For the next part. We are dealing with a solid on solids and an acquisition are unaffected by temperature and so solid ability. Well, the the scene we

In Case one do a nice table here, and we're starting with initial amounts of 1.30 point 800 completar a stable case two. We're starting with initial amounts. 1.33 point 80.20 shift no 0.3 minus X 0.8 When it's x 0.2 plus x x and in case three a plus B in equilibrium a C d. Again. We'll have our eyes table here and we're starting with the initial amounts 2.0 0.800 My ex my sex close X plus X is completed a stable. Okay, So what we're asked to do here is asked to show, um or were asked to order the, um proceeding in terms of equilibrium. Concentration of e increasing concentration of deep so increasing concentration of D. I would ordered these as, um, the lowest concentration of D would be to, um sorry, would be students and small too, followed by one followed by three. So at least two greatest. And the rationale behind this is, um, three will be the greatest do to the highest concentration of a, uh causing the Ford reaction to be the greatest. Um So the Ford reaction will be the fastest in, um, case three. So that would produce the most, uh, D, which is the product. And, uh, to will give a least as the concentration of C present because we have a product will initiate the reverse reaction and consume de so it will use up D, But it will be produced and use it up there for its concentration will decrease. The second part of this question question is to order them in increasing equilibrium, concentration of B. So increasing concentration of B will be three. No, do this three, followed by one followed by two again, least two greatest. And the explanation would just be the opposite of the explanation that we have up above. Just in the reverse order as B is a reactant on, it would be the opposite, as opposed to D being the product


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