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# 2. Uridine diphosphate(UDP) linked sugars are referred to as activated sugar nucleotides in which the anomeric carbon is linked to the diphosphate of the nucleotide...

## Question

###### 2. Uridine diphosphate(UDP) linked sugars are referred to as activated sugar nucleotides in which the anomeric carbon is linked to the diphosphate of the nucleotide: These nucleotide-linked sugars are utilized by glycosyltransferases to form complex oligosaccharides_ Glycosyltransferases catalyze the addition of the sugar from the activated nucleotide to any position on another sugar.a) Draw UDP-linked galactose with the sugar in chair conformation:b) Glycosytlransferases are categorized as inve

2. Uridine diphosphate(UDP) linked sugars are referred to as activated sugar nucleotides in which the anomeric carbon is linked to the diphosphate of the nucleotide: These nucleotide-linked sugars are utilized by glycosyltransferases to form complex oligosaccharides_ Glycosyltransferases catalyze the addition of the sugar from the activated nucleotide to any position on another sugar. a) Draw UDP-linked galactose with the sugar in chair conformation: b) Glycosytlransferases are categorized as inverting or retaining enzymes which either invert or retain the stereochemistry of the sugar when it is transferred from UDP to another sugar: Draw simple mechanism showing the inverting mechanism for the formation of B-galactopyranosyl (1-74)-8 glucopyranose_ You should know which is the acceptor sugar and which is the donated sugar based on the above information: c) Glycosyltransferase reactions are thermodynamically favorable: In order for this to be the case what do you think the approximate dGc' of a glycosidic linkage and why?

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