5

Draw all pcssible eliminaticn products for the following molecule and circle the major praduct Tihis will be graded based on your work)Edit Viev Insert Formal Tools...

Question

Draw all pcssible eliminaticn products for the following molecule and circle the major praduct Tihis will be graded based on your work)Edit Viev Insert Formal Tools Table12ptParagraphwords

Draw all pcssible eliminaticn products for the following molecule and circle the major praduct Tihis will be graded based on your work) Edit Viev Insert Formal Tools Table 12pt Paragraph words



Answers

Draw in all the carbon and hydrogen atoms in each molecule.

Um the first reaction off the ankle with a spear is ah, secondary alcohol. And so it will happen through eyes in one mechanism. Which means that we found the car broke a tie in, and so will the product will be arrested. Mixture. Um, the second reaction over here is a primary alcohol s. Oh, there it will substitute the ah wage with a chlorine. And because it's a primary alcohol, so the mechanism will follow as into mechanism will happen. And from the inversion off the Cairo center and so the product So this is, uh are configuration and the product will have as configurations. Um, so the first step of this reaction will be for me Sea air would have appeared in and then ah, chlorine, we're attack and the mechanism is s And two And so the consequence The product will be inversion of Cairo Center. So this is our configuration and the product will have, uh, sorry. Hydrogen off and scoring so the brothers would be s configuration. So the first step over here will farm Toxie late o T s second reaction will be as until mechanism in which I would die The tank and this one is a living group. And so, as you can see that the configuration over here is Arthur and the product is s.

This question asked us for all of the mama chlorination products, including stereo I summers that could be formed by chlorinating in this compound. So I've got 10 basic structures drawn here, So there are going to be 10 products. Eso they see what we're gonna do is look for all of the unique places we could put a Corinne and then consider each ones, uh, stereo chemistry. See if it's creating any stereo centers. Um, either at the scoring with the carbon of the Korean or another place. So here this carbon is not being service center, but this one is So this does give us a stereo center on that central carbon there so we could have it both ways. So there's two of our products those Iranians humors. Then we will look at the next carbon, which is in the middle here. So if we put a corporation on this would deceive reformist area center and don't because we don't have four different groups on, remember that a Carl's when I need four different groups, these two methods are identical, and then we have this whole other side over here. But because we have those two identical Michael's. We don't have four different groups, so it's not Carl, so that is not a serious center. Then we can put one over here and remember that we have an H on that carbon as well. You know, do have four different groups. We have the Korean hydrogen dive purple and another group over there. So that will give us two different stereo I summers to any and tumors. Then I'm going to the next carbon over here, we have two identical ethyl groups right here and here. So this is not going to create a service. Centers about one is on its own. Um and then if we go Teoh the next carbon on one of these apple groups like this Now we're not creating stories center on that carbon. But on that central carbon, the one we put a chlorine on last time this one right here, this will become a stereo center, just like in the first couple of structures that we did, that Central Carbon becomes the serious center because of the other one. So makes those two apple groups different. And then same thing with this end, metal Earth's and carbon on the fl group. This central carbon will become a stereo center once again because we're now making these two identical medical groups different. Uh, these are called pro Cairo centres, so we have a few of them in this molecule. But there is our last set of structures, another pair of finance humors.

In order to better draw thes structures so they represent miso structures. We need to first recall the definition of a miso structure at me. So structure or compound is going to have a least to Cairo centers and a plane of symmetry. So the molecule itself is a Cairo despite having to Cairo ality centers. So for the first molecule, if we were to draw it such that we have both of these coming out of the plane. Both of these hydroxyl groups going into the plane. Then we see a plane of symmetry right here in the middle. The next one. If we have the both metal groups coming out of the plane, we see a plane of symmetry right where I drew the dotted line. And for the last one, if we have both metal groups coming out of the plane, you should be able to see a plane of symmetry right here. This one has to Cairo ality centers. This one has to Cairo ality centers. This one has to Cairo ality centers

This is the answer to Chapter 21. Problem number 14 from the Smith Organic Chemistry textbook. Um, and in this problem, we're asked to draw the product of two reactions on we are asked specifically to include stereo chemistry. I mean, these are both nuclear filic additions to key tones. Um, and so sodium bora hydride and methanol are going to reduce a key tone, um, to an alcohol. Um, but really, the mechanism is that, er certain border hydride delivers a hydride, um, a za nuclear file. And then the work up gives you the alcohol on dhe. So I think the way to do these is first to just draw the products on, then to worry about incorporated stereo chemistry. So what you end up with for a Is this where you've delivered a hydride? And then the work of a ZAY said gives the alcohol, Um, and of course, this Corbin is now a Cairo carbon. It has four different bonds. So, um, when we go to include the stereo chemistry, so there's there's no selectivity in this starting bora hydride. There are ways to get selectivity in this reaction, but these particular conditions do not impart any selectivity. So what we're going to get is both Ah, 50 50 mixture of the possible products. So, um oops. There we go. So we may see the hydrogen dashed and the alcohol wedged, or vice versa. So hydrogen wedged and the alcohol dashed. Okay. And so then likewise for B. Um, this is a green erred on. And there's no selectivity in this graveyard, either. Eso again. I'll start by just drawing the products or yes, rather the product. Um, so the green eared is going to give us a new alcohol and the added green, you're free agent. Okay. And then when we go to incorporate stereo chemistry again because we don't have selectivity in this variant, we're going to see a mixture so we could get the alcohol wedged. Oops. Uh, and the green eared product dashed. Or we could get the other configuration. Yeah, hold dashed. And the addition products on away. Ridge. Uh, and so this this tert beautiful groom, The stereo chemistry here wasn't specified in, um, in the beginning, in the starting material. But of course, there would be stereo chemistry there. A cz Well, um, so we can just put that on a dash in both Because it's always going to be Sisto, one of these groups and trans to the other. Um, then and there's no way to say which it will be without introducing some some so activity into this reaction somewhere s O if we may get wedged both times that accounts for for all possibilities here. Um okay. Yeah. So that's the answer to Chapter 21. Problem number 14.


Similar Solved Questions

5 answers
Click the draw structure" button to launch the drawing utility:Draw the product of the following reaction:[1] DIBAL-H CH;CHzCHz-CN [2HHz0draw stnuciure
Click the draw structure" button to launch the drawing utility: Draw the product of the following reaction: [1] DIBAL-H CH;CHzCHz-CN [2HHz0 draw stnuciure...
5 answers
Cpon observing an interference pattern produced onto calculate the wavelength of the light? screen, how could you L_2]
Cpon observing an interference pattern produced onto calculate the wavelength of the light? screen, how could you L_2]...
5 answers
20 points 4) For the system indicated below; a) Draw the block diagram of the system below showing all states, input and output; b) Represent the system shown in Observable Canonical form (clearly indicate what A, B, C, D matrices are) and draw the block diagram of the system showing all states, input and output:X1 xz] -[~2 _41 Ez]+[Hluc)u(t) unit step functionX1 y(t) = [2 5] [xzL(31- [I Xz
20 points 4) For the system indicated below; a) Draw the block diagram of the system below showing all states, input and output; b) Represent the system shown in Observable Canonical form (clearly indicate what A, B, C, D matrices are) and draw the block diagram of the system showing all states, inp...
5 answers
Write equations for the reaction of BFz with: (Label the Lewis acids and Lewis bases; identifying the nucleophile and electrophile)DiethylamineDimethyl ether
Write equations for the reaction of BFz with: (Label the Lewis acids and Lewis bases; identifying the nucleophile and electrophile) Diethylamine Dimethyl ether...
5 answers
02) GWVcn -L; 4 Find 649iy Iur thee orthoganal complement of the TOw space of A What /s the ditenston af the Tow ~puce of4 What (s the nullity of ^ ? (.e dimcnslon of null spucc a€ 4,not tle numhtr l zcto--mits
02) GWVcn -L; 4 Find 649iy Iur thee orthoganal complement of the TOw space of A What /s the ditenston af the Tow ~puce of4 What (s the nullity of ^ ? (.e dimcnslon of null spucc a€ 4,not tle numhtr l zcto--mits...
5 answers
Express all of your answers in standard form. Use radicals (roots), not decimals to express your answers_ a) Find all complex numbers z where z 28. b) For each value of z you found in part a), find all complex numbers where w? -182. Please leave the answer boxes blank:
Express all of your answers in standard form. Use radicals (roots), not decimals to express your answers_ a) Find all complex numbers z where z 28. b) For each value of z you found in part a), find all complex numbers where w? -182. Please leave the answer boxes blank:...
5 answers
Question43 ptsA0.250 M solution of HF isat equilibrium: Calculate the [Ht] OH] pH; and pOHfor this solution: Ka = 7.20x 10"4. SHOWWORKHTML [email protected] 6 E 12pt ParagraphI 4 A - @ - I = =222 E - 2 D X 0 @ D]wordsQuestlon 51ptsA weal acid with molarity = 0.115 MHX was found tohave pH = 3.87. Calculate the ionization constant; Ka: SHOWWORKHTML EditoreaI 4 A - A - I = 2 22 2 8 v 0 G @06 12ptParagraphwords
Question4 3 pts A0.250 M solution of HF isat equilibrium: Calculate the [Ht] OH] pH; and pOHfor this solution: Ka = 7.20x 10"4. SHOWWORK HTML [email protected] 6 E 12pt Paragraph I 4 A - @ - I = =222 E - 2 D X 0 @ D] words Questlon 5 1pts A weal acid with molarity = 0.115 MHX was found tohave pH = 3.87....
5 answers
3. lim ex In(x + 1) T0 +
3. lim ex In(x + 1) T0 +...
5 answers
If np and nq25 estimate Pife "er than 6) with13 and0,5 by using the notma cistnoutoracproximatonthe binomial distrbution; ii np =then state that the norma 'pproximation not suitableSelect the correct choice below and necessanthe ansive box complete your choice .P(fewer Ihan 6) = Round to four decimal places needed ) 0 B. The normal approximation suitable
If np and nq25 estimate Pife "er than 6) with 13 and 0,5 by using the notma cistnoutor acproximaton the binomial distrbution; ii np = then state that the norma 'pproximation not suitable Select the correct choice below and necessan the ansive box complete your choice . P(fewer Ihan 6) = R...
5 answers
Integratef GO5 8 cot? 0 de
Integrate f GO5 8 cot? 0 de...
1 answers
Calculate the magnetic flux through the area enclosed by a 300 -turn, $7.20-\mathrm{mH}$ coil when the current in the coil is 10.0 $\mathrm{mA}$ .
Calculate the magnetic flux through the area enclosed by a 300 -turn, $7.20-\mathrm{mH}$ coil when the current in the coil is 10.0 $\mathrm{mA}$ ....
1 answers
In Exercises 59-64, (a) write the trigonometric forms of the complex numbers, (b) perform the indicated operation using the trigonometric forms, and (c) perform the indicated operation using the standard forms, and check your result with that of part (b). $(2\ +\ 2i)(1\ -\ i)$
In Exercises 59-64, (a) write the trigonometric forms of the complex numbers, (b) perform the indicated operation using the trigonometric forms, and (c) perform the indicated operation using the standard forms, and check your result with that of part (b). $(2\ +\ 2i)(1\ -\ i)$...
5 answers
Var ( YIx) Ely Ix) [E(YIx)i ElyIx) [2y" f(ylz) dy [YEepi "5.2y-0+] 4y esh*' '[Jop[2+2+y] 49 5/27' '[yexi-ey*^ 2793 dy 5/1 7" 2+y +24-43 dy Br Ly"exp[-1+ 527 * 3- 23dy 'Cyexp[-2ly3 2ly-#1 dy U = 2y- e5h1z' [ y* e 28y Br (J y "5)" 44 4 '[s= 9" 4tz (0+z) Uh du 5 2[ V/i 7 e "2uze dy [ 'fve" 3T
Var ( YIx) Ely Ix) [E(YIx)i ElyIx) [2y" f(ylz) dy [YEepi "5.2y-0+] 4y esh*' '[Jop[2+2+y] 49 5/27' '[yexi-ey*^ 2793 dy 5/1 7" 2+y +24-43 dy Br Ly"exp[-1+ 527 * 3- 23dy 'Cyexp[-2ly3 2ly-#1 dy U = 2y- e5h1z' [ y* e 28y Br (J y "5)" 44 4 '...
5 answers
Find the derivative of the function_f(x)+ 3{x)
Find the derivative of the function_ f(x) + 3 {x)...

-- 0.022036--