Question
@Lnowt J9Unknown numoer Solvent: MeOH Table Data summary (use as many TOvs as necessary accommodate your majorfimportant peaks In the space below draw the structures tor the fragments at each mZ Comment on any unexpected or missing peaks You may continue onto the back if ycu need the space_ INote: tnis form must be typed, but sinuctures may be crakn by hand). Please delete the example row Rulatye InlenaK-77louon 235 "D GTNTDkl jiot
@Lnowt J9 Unknown numoer Solvent: MeOH Table Data summary (use as many TOvs as necessary accommodate your majorfimportant peaks In the space below draw the structures tor the fragments at each mZ Comment on any unexpected or missing peaks You may continue onto the back if ycu need the space_ INote: tnis form must be typed, but sinuctures may be crakn by hand). Please delete the example row Rulatye InlenaK-77louon 235 "D GTNTDkl jiot


Answers
For each compound, assign likely structures to the fragments at each $m/z$ value, and explain how each fragment is formed.
a. $C_6H_5CH_2CH_2OH$: peaks at $m/z$ = 104, 91
b. $CH_2=C(CH_3)CH_2CH_2OH$: peaks at $m/z$ = 71 , 68, 41 , 31
No more. Three through six. Thank you. Die. Six degradation for happen are so more your thing. He's strapped in like this. Or 1234567 Yeah, so this floor six. Daniel, I don't the animal there you must values 87 17 100 in 11. I want the basics. Org They didn't different Ignatz Last victim. No, no, this point b the print. In the months since the morgue remarks of Nexus one before know the difference will be 143 poor minus 2600 If ICS 1 40 poor. Why this one? 26 should respond toe for best ball 18 So in our cooperating. But naturally we can think, I guess the immortal a water mark Your so this fragment have you, uh, one for defense and by me equals 1 26 The 2nd, 111 should get us onto So one good if it's minus 11 So 1 26 What is 1 11 Should be equal toe 15 So we can think of Oh, another quickly rates feel So this metal loss of this middle group to give and then God you the blessed are you stable one. So this is and y equals 11 No, they have 87. No. When Brunton combos. Well, it's always so in the grace of alcohol's, uh, second York, Ahold's one of the got a busy pregnant business. The loss of this this is us on it. The previous of this tape. This is very, very good. A critical, uh, security arc. A horse that will give you a pregnant he used to dot less. Well, it's your velocity. So this is having the last video 87. So this is you, said the Republicans. The actual so during sex, it's a good one and curdled.
Here we will be looking at structures for compounds that fit the following data we have listed below. So, firstly, will he ranchito a massive 86 then we also have fragment masses. Secondly, we're looking for a alcohol with a massive 88 again we have some fragment masses. So the 1st 1 the lockout, is our key tone example. So, as you can see, I've drawn out my structure. We have a five carbon chain with a key turn on the second common. Now we can tell it to keep done because we have to our groups where neither off them are protons. They are both carbons. And then we come to cipher are fragments as being all ch three on ask th three ch two, ch two. Secondly, we can look at our second example while we're looking at an alcohol with a massive 88. So this full carbon chain with a Mithal substitution on a alcohol substitution on the second carbon corresponds to the massive 88 then we have off fragments that corresponds to several different cut things off the molecule out several different points that generate thes slightly different muscles we observe, But just like I said, here's my far structure of my key tone on this is my second structure for my alcohol.
So here we're looking to make synthetic cuts for fragments that we might expect in Dimas Spectra off the following molecules. So fastly, just to cover a definition in spectrometry fragments is the dissociation off energetically unstable molecular irons formed when passing the molecules in the ionization chamber of a mass spectrometer. So the fragments of a molecule do cause a unique pattern in the mass spectrum. So when we're looking up fragments, we need to assign a synthetic cuts that would allow us to form are fragments. So, for example, in this first structure, while we have a a brunch hydrocarbon, where we also have a key toe we may cut here on, that would generate two different fragments. We could also cut up this site so that just two examples about we could cut in all the to generate fragments. And there are no second monkey. We have tried, he thought, Amy so obviously. But there's only really Ron sort of cut that we can make here, and that is too removed in exile group
Let's draw the structure for each of the following molecules and we're going to use the rate stereo chemistry configuration for a zed 135 tribe Romo to Pantene position or double bond here, and we'll have zed configuration. Um C h two b r h b r and ch two ch two br So there would be zed 135 tribe Romo to Pantene. Could be e one to die, bro Mo three Method to heck scene. Here's our structure for C s one brome 01 chloral b team the carbon chlorine. Awesome promo hydrogen three ch two c h two ch three for D are 13 die brome Oh, heck scene So the h each to siege to be our ch two ch two ch three And for e s one claro to Prepon Oh, eight. See three h to seek out So there. And so this would be ohh for the alcohol. So s one Clara to pro panel And there are are structures drawn with the appropriate stereo stereo chemistry designation