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C) Identily Ihe reagents represented by letlers A and B in the reactions below_Marks)OHOHCozhOCH;...

Question

C) Identily Ihe reagents represented by letlers A and B in the reactions below_Marks)OHOHCozhOCH;

c) Identily Ihe reagents represented by letlers A and B in the reactions below_ Marks) OH OH Cozh OCH;



Answers

Draw the products formed when $\textbf{A}$ and $\textbf{B}$ are treated with each of the following reagents: (a) Br$_2$, FeBr$_3$; (b) HNO$_3$, H$_2$SO$_4$; (c) CH$_3$CH$_2$COCI, AICl$_3$

Okay sweater reacts one ethyl cycle vaccine with the following reagents and the first one is HBR just cycle I was a ring the endings and are keen And hex is 6, 6 carpenter ring with an ethyl substitute and the first one is up is HBR So this is a simple electra falcon distraction. And if you put the hydrogen on the left substitute carbon so we get a more stable carbon cat on and that's committed carbon with the most are groups. So as a result of the hydrogen on this carbon Is this one is territory has more or groups so filled with the mechanism. We'll have a carbon county right here partner here and Bernie is going to attack it to give us the final product of remote ethel Or one bromo 1 ethyl second vaccine. Next one is um with HPR peroxide. And if we add peroxide it's gonna put the burning or the carbon capture and lost substitute carbon. This case would be secondary to tertiary. So when reacting this with peroxide. Yes, we're gonna get this product. Next one is um hydrogen gas and plotting catalyst. And so that is a reducing agent. It can be used to reduce akin's out of hides and cartoons. It's a similar strength to Sunni Berhad road and can also use palladium or nickel as well with hydrogen gas. It's gonna reduce the key in this case. Pos ethel cycle accident X one is on to be hydro operation. It's gonna have the alcohol to a substitute carbon and he's their agents. This is over th F tetra hydro if you're on then we have peroxide and hydroxide and the last one is BR two and declare a thin she's so you can all this is known as the halo hygiene reaction. You also you see also another non a non aggressive solvent like mm try chlorine, methane. But it's going to add the intelligence and anti edition just having one front and one of the back. If we have this parameter in the front, the catholic group is going to be the back and this album be it back be the hodgins in the front. You could also draw the diastolic for this as well. So if the Birmingham is one decides to the appears three and the other group is for Yeah to go from one or 2 And then 2- 3. 3- one ignoring 4. It's gonna be our Sit look at this one. It's going to be one That's two, this is three and the hydrogen that is for so you're from one or 2 to 33 to one. It seems like it's S but hodgins in the front. It's also going to be our as well. It's gonna draw the finance for which want to reverse all the carol centers. I mean beyond configuration of the carol centers, you're gonna put the broom in the front. I mean Berman and back ethel on the front. We're gonna put the sperm in the front and the hydrogen in the back. If you want to draw the Diagram er recent changes configuration of one Carl Center. So if you leave this one, the same grooming is going to be the front I think is going to remain in the back this time bringing to the front Hodgins in the back and as a result it has the opposite configuration. This is the R. And as a result is going to be S. And same here too. So this is gonna be the handsomer and this is the diet history or dive staring her.

Right. Okay. In this problem, we're starting with this. He turn and subjecting it to a variety of reaction conditions. The first being studying for a hydride and methanol. Of course. This one we imagine this is just the hydride talking the cardinal directly. Then we'll generate this secondary alcohol. Second condition they would like you to use lift them aluminum hydride water. Actually, this reactivity is the exact same. It's just slightly more reducing conditions. It's also just a H minus precursor. We'll attack directly and get you to the same products. Percy. They want you to use methyl grenier followed by water. This method Grenier will attack directly and you'll generate this tertiary alcohol for part D. I have a running at a Stacy. Let's see how we just read right here. Okay. D We're using thiss finalist, IAM re agent and then water. Of course, this is just going to act as your carbon nuclear file, generate this tertiary alcohol and finally, they'd like to subjected to some oxidizing conditions and Crimeans 76 feces. And this is actually already the most oxidized condition. So nothing will happen in the face for be. We actually have a substituted psycho ex sane. It looks like we have and eat there at this position. This is on the of all this on the dash position, then on carbon 123 or meta to it. We have it seems to be here, my fool, Us there, this meth less There's actually on the down position. Okay, So knowing that are going to subject it to the same reaction conditions First song. We have stadium for hydride and methanol. Of course, this is going to reduce down your carbon. You'll all the way down to pee primary alcohol because it's the card in there. Okay. And this can also be accessed using the stronger reducing with him Aluminum hydride, followed by You're a caseworker can also Tahsin methyl Grenier missile, of course. Attack your carbon. You'll directly to generate. Actually, this is going to have been twice right. I still have the tertiary alcohol. Next we have. So this will have to be draw starting material finalised the, um and say your final group is going to attack directly, and that will add twice. Second step is decreased. Work up, of course, of two found groups here finally under very oxidizing conditions again. Our entire species is and you know, socks. I state, so you won't see oxidation of to say car box like acid. So this is again no reaction.

Going in this problem? Where do any different the products off? Really actions? All the three reactions are build off reactions. See OOCL. There's an English of one carbon here and the third one is Have you got my living guaranteed? Now here in America we have toe reconstitution is supposed to occur Indeed first of funds the Syria my own and then protects you I fall invited system So this is the problem for many questions. Similarly, in the second case, it quantitatively Yes. Really seen my name? A six month waiting in the third place. It is a greater al collision. Reaction were invited. It found a mental Garbo Gadio Here, this goes up informs American marketing on this. Yes, you. I'm bomb C H two see Ancient 36. These are the

If you have even drug addiction region products for what gave me here, See, is three. Oh, see is three less be a three. So the product is be a three. See is three and C is three here, see? Is three see his three or sees three with oxygen containing lone pairs. Egg eggs is the lowest bays ladies basis and the tree is the ladies as it in solution for part b be here. Here, See is three oh, incision Having long piers see is three plus it's you in the productive. The product of direction is CS three oxygen and C is three less chlorine and nine this bean abstract pro con Francia And this bone shift words chlorine because cloning small and after negative. And here it's here is and CEO ease. It's here is a proton Donating? Yes, it see is three always history. It is a based accepting the for con in Bob. See, we have see is three in its two nitrogen hating loan. Pierre does a l. C l three The product of the reaction is and he sees three finish to is the Levis base living space here and donating lone pairs of electrons deliveries s it So the product form is here like this


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