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1238AM Fri Not 200326T0o 20 "lpbHow cpuldyou prepare the following cyclcherencnes by combinina Stork enamine reaction Yithan Intramolecular Idol concensation?C...

Question

1238AM Fri Not 200326T0o 20 "lpbHow cpuldyou prepare the following cyclcherencnes by combinina Stork enamine reaction Yithan Intramolecular Idol concensation?CHa

1238AM Fri Not 20 0326 T 0o 20 "lpb How cpuldyou prepare the following cyclcherencnes by combinina Stork enamine reaction Yithan Intramolecular Idol concensation? CHa



Answers

How could you prepare the following cyclohexenones by combining a Stork enamine reaction with an intramolecular aldol condensation? (See Problem 23.43.)

In this problem, B react with and the and C 10 and C 10 at 21 tho at plus to give the productive NC five H 11. See Triple one, C ch two ch two ch two, C h o h c h o h c 10 As 21 n. So according to the option here, option B, each correct answer, option D. Age, correct answer for this problem, I hope you understand the reaction.

Hillary won. Today we're doing Chapter 18 Problems 78 and this wall masses to draw the step ways mechanism for the falling intra molecular civilisation in the formation of product, Eh? So we see here is that we have a Louis acid or some sort of A and we're closing up. Two rings were closing up this rank and also closing up their strength. So first, let's use H ey and probably any anything that could be a pro native. So right away we see this alcohol can pick up one of the protons I have always too like this. And now we have pro needed water with water does not like to have a positive charge. What's gonna happen is that this water just going to spontaneously fall off. So we have a caramel Catalan intermediate with water. So now we have this calculable bond that connect as a nuclear fall go through this carbon with us to election from Spy bond and former first cyclical Morty strong love better. But now we have a Carvel tad and being formed here. So now, actually, what we see is that we actually have advancing ring With the election donating group for both of these ortho positions on this parent position. So we can actually go through this para position to election Filic Air Max Substitution to neutralize this Carl cat and mouse form from this attack in the process, we know just close the second ring up. But now we actually have now, Kara Time Intermediate that forms here. This carbon here has a proton. Then we use the h over H A butt is acid catalyzed reaction. So we need to reform that each, eh? So this is a minus is going to pick up this proton to free form our ass A catalyst making about me Make a bonny break a bond and regain Ara Metis ity onto our Benzino plus be reformed now h ey and reformed final product A here

Is this arrangement superficial or enter official first. Like uh, sure, the floor off electricals. The six Alertness in Wolf Tool by undertones. Two Sigma electrons in the long prayer. So they're six electrodes which respond to the automatic transition state. We need to keep symmetry off homer, which is achieved by the superficial there against Lee.

So if you look at the different code owns very Chuck these amino acids, this is the list of each of the possible court wants just taking the 1st 1 through each of these, we could make a possible and where any secrets that would good for angiotensin two. So an example would be checking you. See you. She You You a new being Here, you see? You, see you And you. This is just one possible sequence so you could make one with two. Is Mormon one from here? One from here, one from here. So there are many different possible of these, but doesn't one possibility that could for and you're attempting to?


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