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QUESTION 1What is the relationship of the molecules below? 9HEnantiomersDiastereomersThey are the sameQUESTION 2What is the relationship of the molecules below?Enan...

Question

QUESTION 1What is the relationship of the molecules below? 9HEnantiomersDiastereomersThey are the sameQUESTION 2What is the relationship of the molecules below?EnantiomersDiastereomersThey are the sameQUESTION 3What is the relationship of the molecules below? Lon Ho= ~Oh Ho-EnantiomersDiastereomersThey are the same

QUESTION 1 What is the relationship of the molecules below? 9H Enantiomers Diastereomers They are the same QUESTION 2 What is the relationship of the molecules below? Enantiomers Diastereomers They are the same QUESTION 3 What is the relationship of the molecules below? Lon Ho= ~Oh Ho- Enantiomers Diastereomers They are the same



Answers

State how each pair of compounds is related. Are they enantiomers, diastereomers, constitutional isomers, or identical?

So for this question, we are supposed to see if the following structures are in, in tumors or identical. A really good way to see if there are one or the other is by knowing the cereal chemistry. So if both of them are are or as then that means that they are identical. If one is S and one is our, then that just means that they are an anti MERS. So for this first one, um, we are just going to organize priorities real quick. So first is oxygen and then to three, four and then for this one it would be oxygen again and then to three four. Mhm. Um from 1 to 2 to 3 then it's like this. The last priority is undead ash meaning that this is accurate. So the sport is as um on this one, it would be 123 The lowest priority is not on wet, on dash. It's on wet, meaning that this is not really accurate. And instead of being as it's going to be our because we're going to flip it. So since one is us and one is are these two would be an and humorous? No, I'm moving on to the following one. We have been same thing. We organize the priorities. C L. Goes first and then br Yeah. Along with the most carbons and then at least cartons 123 lowest priority is not in dash. So it's an art or and same thing with this one, we have one. You have to three and four For this. One of the lowest priority is an dash. So one To because you have to avoid passing through three and then it goes that way, meaning that this goes clockwise. This is also our so these two are identical. Okay, moving on to see uh it's priorities 1st. 1st is than we are. Yeah. See in the last H. Yeah the dash is not in the lowest priority. So we're going to have to flip it at the end, this is going counterclockwise but we have to flip it with this are and then here, oh God first br see. And then each same thing as before he goes this way. But we have to flip it because the lowest is not a dash. So instead of going counterclockwise we're going to say that it's going clockwise so far as well. This one is identical. And for d we have once you first one two seats one c. and then one age than 23 It's going counter, it's going clockwise. So this one C. L. Juice, ease one C. And then one age 123 It's also going clockwise and Transport Art. These are I did

Hi everyone. So in this question they asked consider the following two molecules which are the following best describes the relation of the two molecules. So, and our options oh, shut B is correct. Very much die stereo. The the two compounds the two compounds two compounds. Mhm compounds see wage and Yeah. Yeah. Mm. Uh huh. See your age or dice. Video months. Night studio Merce. Yes, that is. Thank you. Because no, there are non mirror images. Very odd. Non mirror images. Yeah. Yeah. Before an arrangement of default in arrangement of arrangement of uh huh. There are times in space that our dumps in space. Thanks love.

In question 62. They give us several pairs of compounds, and they want us to determine whether or not these pairs of compounds are identical and an tumors dia hysteria MERS constitutional I summers or not any ice, um, er of each other at all. As you recall, an anti immerse will be mirror images of each other. Identical just means that the same molecule dia stereo members means they have at least two stereo genic centers. And they're not super imposible constitutionalism. Er's means that they just have the same chemical formula. And then not I summers. It all means they would not have the same chemical formula. So for the first two, we have these structures. We have what appears to be the same molecule. However, in one case we have this carbon coming out of the plane, and in the other case, we have this carbon going into the plane. So because they have the same structure, same chemical formula, we just have a difference in whether it is an R or an s configuration for the stereo genic center. Then, by definition, these would be an anti immerse of each other. We could prove that by taking this molecule here and flipping it 180 degrees. If we flip it 180 degrees that this carbon is now going to be coming out of the plane and it will appear is the mirror image of this one for the next pair. We have these two molecules. They obviously do not look the same so they can't be Dia Steri emerged. They can't be identical and they can't be an anti Immers. But they still could be Constitutionalist Summers if they have the same chemical formula. This one has seven carbons and 14 hydrogen. This one has seven carbons and 14 hydrants. Hydrogen. So these air constitutionalism er's of each other for the next two molecules, We have this one where the O. H. Is coming out of the plane, the hydrogen going into the plane, and then we have the ohh going into the plane and the hydrogen coming out of the plane. But off of this carbon, we have a C H O group in off of this one. We just have a metal group. So if we were to draw the next structure which looks like this carbon going into the plane coming out of the plane. Then we've got our methyl group carbon, our sorry hydrogen going into the plane and the hydroxyl group coming out of the plane. As they're written, we see that they are not stereo I summers of each other. We see that I'm sorry. They're not an anti immerse of each other. This is attempting to be the mirror image, but we have a hydroxyl group going into the plane and the hydrogen going into the plane. However, if we look at this carbon, we have ah, hydrogen going into the plane. And over here, we have a hydrogen going into the plane Hydroxyl group coming out hydroxyl group coming out. So this ends up having a mirror image of this. But this carbon is not the mirror image of this carbon, so they can't be in an tumors, but they do have mhm stereo genic centers and they do have the same chemical formulas. So they have to be. They can't be identical. Can't be constitutional because they're not arranged the same. They must be dia stereo murders of each other for the next two. We have this molecule and this molecule we see that they have a different number of double bonds, so they can't be the same. They can't be an ant humorous of each other because they don't look like mirror images because the bonds air in different places so they can't be dia steri MERS. So let's see if their chemical formulas they're the same. This first one has chemical formula C eight h 10. The second one is CH. 12. So these air not even I summers of each other. We then go to the next one where we have this sigh click structure. We see that the first one drawn. Let's see, this is the way the second one was drawn. I took the liberty of rotating this one about 120 degrees. And when I rotate this 1 120 degrees, it now looks like this. And that, hopefully is obvious is a mirror image of this one. So these are an anti Amar's for the next one for F. We have the structure hydrogen coming out of the plane roaming going into the plane, and then we have this structure. And so what I did is just draw it the way it is. But if I were to rotate this 100 and 9.5 degrees this way, I'd still had the bro mean going out of the plane. I would have put the iodine now in the plane so it would appear in the plane here. And then I would have the hydrogen, which is in the plane here now, coming out of the plane. And when I do that, it ends up being the mirror image of this one. So these would be an anti Immers, then for part G. I have this structure and I have this structure. And as they are drawn, we see that if we were to which I did hear, I rotated this. If you compare it to what's in the textbook, I rotated this carbon around this single bond. Single bonds can rotate so that the, um, methyl group that was in the plane going down is now in the plane going up. So I rotated this exactly 180 degrees, which puts this metal group up, puts the borough mean now into the plane and the hydrogen coming out of the plane. When I do that, hopefully it's obvious that You see that this molecule as is, is the same as this one right here. And all I needed to dio was rotate this 180 degrees. Now I have chair structures. Hopefully it's obvious that the stereo chemistry here and here are the same, but different here and here. So if we have to steri agenda centers and one of them is different than by definition, we would have a to die a stereo MERS. However, what's different with this is this Steri, a genic center here, has one group that it is equal to the other group. This group is equal to this group. So we would say that these are a Cairo and simply just our constitutional I summers of each other because neither one of these would really be considered stereo genic centers. Now, if we look at I, we have two molecules that do look completely different from each other. However, one is written in the chair structure and one is not. We have both of these metal groups coming out of the plane and when written in the chair structure, we have one going down and one going out. So this would correspond to cysts. This would correspond to trans. If we have system trans arrangements, these would be die Osteria MERS of each other. Now for the last one J, we have this structure and we have this structure and hopefully you notice they're not the same molecules here. The br is attached, Teoh a carbon here, the briars attached to the central carbon. So if they have the same chemical formulas, they would be Constitutionalist Summers, which they do. If they had different chemical formulas, they would not be I summers of each other.

So we're continuing to work with Stereo is a MERS and so this is defined as the branch of chemistry that is concerned with a three dimensional arrangement of atoms and molecules in space and how this effects are chemical reactivity. So starting with example, A to the compounds are the same and they have the S configuration. If we rotate them, you can see that we have the same compound moving on to the second example we have financial mus, so these are non super impossible mirror images. So that example is Dia stereo Eisner's. They are not super imposible, non mirror images. So for our next example, we have the one s thio ask configuration and now the same compound. Just simply rotating one of them will reveal that to us. Next, we have a pair off dia stereo. I summers So we have the two configurations the one Earth to us one our to our next we have constitutionalism er's So this means that we have the same molecular formula A different arrangement of atoms, different connectivity of atoms mixed you up, Dia Steri rice. Once again following this, we have a non Chalmers. Next we have same compound. Next we have different compliments of the same molecule. Almost a the end. Now with our list, we have financials. So with this one that was came I missed a Kyra page again. So we have Dia story. Oh, is a MERS. Well, we have the same compound with and we have diced terrorism er's following And we have constitutionalism er's after and we have oh, peaky left. So we have diced story I summers, Pete, we have the same molecule as we do for Q on both have no Kyrill centers.


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