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Solid silver sulfite and solid silver lodide are equilibrium with solution containing 5.56*10-J M sodium sulfiteCalculate the concentration of iodide ion present in...

Question

Solid silver sulfite and solid silver lodide are equilibrium with solution containing 5.56*10-J M sodium sulfiteCalculate the concentration of iodide ion present in this solution_ [iodide]

Solid silver sulfite and solid silver lodide are equilibrium with solution containing 5.56*10-J M sodium sulfite Calculate the concentration of iodide ion present in this solution_ [iodide]



Answers

What must be the concentration of silver ion in a solution that is in equilibrium with solid silver chloride and that is $0.10 \mathrm{M}$ in $\mathrm{Cl}^{-}$ ?

So now we work on problem one forty two from Chapter seventeen. So here we were told that we have a solution of silver chloride, potassium iodide, mixed or shaken with an excess of silver chloride. Andi need to calculate the concentration of I. I'm Alice. So first, let's write the soy ability Constance for both silver iodide and silver chloride. So chaos P for silver iodide is equal to eight point five one times ten to the minus seventeen. And for silver chloride is one point seven seven times ten to the minus ten. Yeah, so since the value of silver iodide is much lower, it tells us that silver iodide will precipitate when it's shaken with silver chloride and the chloride will go. Chlorine will go into solution. So we say we have excess of silver chloride, so we can assume that all of thie iodide the zero point when Mueller's will be captured by the silver so we can write our equation for the dissociation of silver iodide for silver iodide is followed, plus silver plus, I mean produces silver plus plus I'm minus. Both are obvious so we can write our ice chart. I C E So now this is unusual because we know the concentration of silver iodide and solution because the protest the ID ID from the potassium iodide should be completely used up by silver since it's in excess. So we know that we have zero point one mueller here, and we don't have any of this present. And so we go minus s plus s s zero point one minus s s s. So we write our terms equal to the P. So we get squared over zero point one minus s. And if we can't kill, it s here. We get s is equal to two point nine two times ten to the minus nine Mueller. So by shaking with silver chloride, we reduce the amount of IDA and solution from zero point one mueller down to two point nine two times ten to the

Okay, so we make a conversion there 2.23 g of civil. I'll diet my declined by one more off silver iodide divided by to 24.77 g off. So tired I'd We give 9.29 84 into 10 to the power minus B model since we're all day. So similarity is equal to number of moles or more you in leaders. This will be nine 2984 10 to the power minus three moles. E g I divided by 0.01 m, which is equal to 0.9298. It's more muller.

So this money we're going to be answering question 144 from chapter 17 which asked us to calculate the concentration of eye minus in a solution obtained by shaking 170.1 Mueller Potassium iodide with excess silver chloride. Um, so there to solids that weaken havin solution One is our silver chloride that we're starting with and that has a ke sp of 1.7 southern times turned negative 10. The other is what we've been possibly formed by combining your silver ions and our iodide islands. That would give us silver iodide, which has a K S p. Of eight point by Warren Times 10 to the negative 17 which is smaller than the K s p of silver chloride. So we know that as we shake this solid in this potassium iodide, we're going to be forming the more insoluble solid. Which is that silver iodide I ved. Um So before we're forming that silver iodide from silver irons and I write arounds, we need to form the silver eye on, So we need to look at the dissolving of a juicy L Before we can look at the formation of a G. I So our first icebox in sprayed UCL dissolving the mg plus in seal minus. And we know we have access a Jew seal. Um, so we have plus X plus X, which in equilibrium gives us X and X. So the K s P is just equal to X squared X is the spirit of the ke SP. We get 1.33 times 10 to the negative five Moeller of a G plus in C l minus ions So we can put that in the beginning of our icebox for a G I. So we have that 1.33 counts from the negative five Moeller a G plus and then our 50.1 more I'm minus and then we just have minus X and minus X. Since these are being used up two former solid a g I sew it delivery. We have 1.33 times 10 to the negative by minus X and 100.1 minus at and we can plug these into our expression for the ke sp. So we have our ke SP which was 8.51 times 10 to the negative 17 equal to 1.33 times tell the negative five minus X times 50.1 minus X and we sold for X, we get 1.33 times 10 the negative by which means 100.1 minus X is 0.9 molar.

We're keeping the reaction between two acres. Solution put has a mouth and so fine a tree. When both and mixed together, they phone sit for our guy. We have to weigh out the chemical reaction equation complete. I only Ah, reaction in question. Also the now on nick equation. So that stuff with their chemical reaction you creation. So your spirit straightforward up? Because this is ah, the boat. This basement reactions. So you can just imagine we have Ah, both. Um can we compound this? Which All this for a partner? So we have silver. How did I and those who brief hour potassium nitrate. And this is the most common chemical you question you have seen And for computer. I don't like you creation. We have to show individual lions. So first of all, from coalescing now, would I? Essentially, we have POTUS Himalayan. Reformed I iron super nature. If we have silver and night tree irons. Okay. So one day foam, actually ah, super out guys are solid, so it is no longer to be ironed. Build a silver and other trying to compile a shorter the potassium Lilian and I try India's to exceed sa s and I assign iron. So for that Simone and 90 And they essentially are our spectator. And okay, So where in, Wolf? Until that island like equation, we only have to show the eye and that, actually, we can thank you. Ah, reaction. So we have silver iron from silver nitrate. And then we found out I from protests about guy and full of them. They come by the shoulder to phone silver. Oh, guy for this that are making creation. So for that on regulation, we don't have to show any spectator ion and desist the Ionic equation.


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