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Give the complete mechanism using CAF for the reaction ofo-chloro benzoylchloride treated with EtOH in aqueousacid. How many peaks would be visualized in the 1H and...

Question

Give the complete mechanism using CAF for the reaction ofo-chloro benzoylchloride treated with EtOH in aqueousacid. How many peaks would be visualized in the 1H and 13C NMR foro-chloro benzoylchloride?

Give the complete mechanism using CAF for the reaction of o-chloro benzoylchloride treated with EtOH in aqueous acid. How many peaks would be visualized in the 1H and 13C NMR for o-chloro benzoylchloride?



Answers

a. How many isomers are obtained from the reaction of 2 -pentanone with cthylmagnesium bromide followed by treatment with aqueous acid? b. How many isomers are obtained from the reaction of 2 -pentanone with methylmagnesium bromide followed by treatment with aqueous acid?

Yeah, the reaction off. I see you. Pinot sit talking on that's village in rate. Anyone on reaction with the base for in the database. Any human, um, exist? When? When we get C w ball ball. See, it's two minus. Okay. When this is greater with uh huh Contributed Pito c six Explain double board double 14 I c. Six h way The arts in the Michael Fashion resulting in the formation now c six. It's fine. C w want all see it too, See? 68 12. See it's food. See it all minus C six h five. Mhm. Which on a certification? There's a corresponding dikky tone. See Double 10 it's this ceases Thanks to play That is it. It's e on What? It's minus So it forms. Want to pay for by 15 82 during this reaction, The second reaction anymore Same way cycle. With that I mean self trust you terrain on. You can hear the base, but that forms right again. Know anyone? It is treated with the seeing All right, But we don't are inside rhetoric. Ito Michael. Passion ceases explode and C six It's right here. Cool. Oh, giving what? C C six. It's foe number one. Well minus on D. C. Sees his way, which I want People knew the acid XP. Hey, calm. See everyone go cuz seats right with two double ones. You know I'm here.

Here. The question number seven is first is a how many stool us summers are obtained from the reaction off to bend in on with the title Mad Mission bromide followed by the addition off dilute as it. So I opened the known that is the company's ch tree near something first e So the component given is ch three seen double born oh, siege to siege to earn siege three this conformist stupid you know, And it is the acting weed he told him made mission bromate that means see, do Etch Frank groupies that instrument machine. So the big nerve Agent chicken is this And by this combination, alcohol is fault. So the alcohol which is formed the ease first this reaction and second reaction ensued. Dilute a seat. And by that we're getting the final component that is ch cream. Seen who pressure you Go home, See do Etch Fine. And one more C three h seven this is the tertiary. A goal we're getting out of this job Two reactions on and, uh, this is optically acting. It is because it is having s a magic center and because of this asymmetric centre waterfronts that it can have D and l consumer of charred metal images off each other so we can draw the structure. One good one, one here and one here and run. He's about the plane. One in Spain notably. So here it is. Which group, then? This must concede three group. And here it should be C two h five group and C three at seven. Bees. Yeah, billowed a plea and the media image off. This is another consumer. Optical is somewhat decks trend liberal to Ginny. So which is middle image of this? So we owe broader structure off middle image. We can make the switch and see each tree must be here and the group below the plane is C 37 and ever the plane it should meet. See, do ich fight. And here both are optically acting, so we can see to studio. Is Somerset possible in the first case Me Now come to be in be The question is given that how many street I summers are hoping from the detection off group into known we re tile madness. Ember might followed by the addition of dilute transit. So same reaction is given, but the big nerd agent is different. So the first compound is to Clinton on that is be drop into non retail. Then she double bond Oh, and siege to siege to ch two. This is the component Cuban and it is dependent on and it is directing with me Title mentioned bromide The self you came but shame reminding the first case. So does the retail group just statically it is to make machine and could noted this just no, by these two combination we're getting again tertiary alcohol. But this tertiary alcohol is me tight here again about the steps on the last step in subjection with dilute a set on by that you're getting retain then one carbon, then one which and then one detail coming from the technology agent And this is already presented the molecule sieged job search. So this is the treasury alcohol we're getting on and only one studio s summer is possible. That is not disturbed. I simmer optically active consumer because here to me, tell groups are present. So this is not the estimated carbon. So no question off optical I summers so only one compound we're getting out of this election. That is this compound. Jeez, having told me, take

In this problem, we are asked to give the stereo I summer as possible with each of these reaction paths. So in the first one we have hydrogen and lenders catalyst, which first rewrite relates to a cyst beauty, an assist to beauty always from an AL kind. And then we react with grooming and decorum methane, which results in anti edition. So one would be towards us and the other away from us. We have to remember that the mirrored version of this is always possible. And of course in this case, the only other stereo is summer is the finance humor. For the second problem were asked for the dissolving metal reduction, which creates trans beauty means or trans al kings. In this case trans to beauty, we once again might leave the carbons planner in our depiction and have one grooming come out and the other go into the page. And once again this compound has an anti armor that would also be formed by that last reaction. For the final one. The first reaction with chlorine and die chloral methane, assuming one equivalent will result in the anti edition of the chlorine across the alkaline bond. And the final, the final reaction will result in another edition of halogen is this time bro ming. So we would have the chlorine being anti edition as such and the brahmins filling the remaining positions. Yeah, on the compound. And once again, it would be possible to have the Ananta more because we're adding blooming too, A two beauty in which is a cleaner compound. So once again, we also have, it's an anti more possible, which would simply be done by flipping all the up and down bonds.

In this problem, we are asked to evaluate the stereo I summers obtained from each of the following reaction paths of two butin. So starting at the top, we first react with hydrogen and lenders, catalyst, poison catalyst reactions always result in CIS Calkins. So we have sisters to beauty in from that and then a reaction with roaming and die plural methane will add two equivalents of roaming to the compound. But we have to remember that this hello donation reaction is always resulting in anti edition across the double bond. And so we might have one come out of the page and the other co into the page. But we would also have its mirror image, also known as it's an anti armor form an arrest Simic mixture. The second problem rest first for the dissolving metal reduction, which results in a trans O keane. And thus we might draw again the carbons planer and we'll have anti edition across the double bond, one grooming out the other rooming into the page. And we might consider what nancy more this compound would look like. If we were to draw one, we can have the first carbon go the first roman go into the page, the second remain come out of the page. You'll notice that if we were to rotate this 180° that we would actually have the exact same compound. So this is not a compound within an anti um er And thus this is the only product that we obtain. Mhm. For the reaction of first chlorine will have a Trans Alpine assuming one equivalent. So we'll have one chlorine on one side, one chlorine on the other side, and then again roaming and declare a methane will have anti edition. So we'll force draw the bro means to make sure we get that anti edition 12 1 growing out of the page, the other booming into the page, leaving the chlorine only one spot to occupy. And once again, if we were to draw on an anti emerges compound, it would have rotational symmetry and be identical to our previous compound. So this is the only stereo system are obtained.


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