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1.How would vou prepare the following alcohols using the Grignard Reagent and Aldehyde/Ketonc? INCLUDE ALL THE POSSIBILITIES (10 points)OHOH...

Question

1.How would vou prepare the following alcohols using the Grignard Reagent and Aldehyde/Ketonc? INCLUDE ALL THE POSSIBILITIES (10 points)OHOH

1.How would vou prepare the following alcohols using the Grignard Reagent and Aldehyde/Ketonc? INCLUDE ALL THE POSSIBILITIES (10 points) OH OH



Answers

List three different sets of reagents (a carbonyl compound and a Grignard reagent) that could be used to prepare each of the following tertiary alcohols:

So one of the advantages things about adding a green Udrih agent to end Esther is that we can have the addition of two carbon carbon bonds. So unless we're using a mix Grenier, which is not goingto Ulis high synthetic results, we need a solitary Granier that is gonna add to of this name things. So for this question oh, we need to identify the two, um, substitue into the central carbon that were added So in this one. Oh, outlined them in blue was likely this one. And this one were green. You re agents because they added the same. So that means our, um our Esther looks something like this. Three plus, and then our Greenert waas excess. Ah, see, age three MGB are now I can run through the mechanism on the 1st 1 so we form the carbon carbon bonds. Which leaves us with this structure or this Tetra he Jilin Immediate. The best leaving group is Theis eventual Alcock side. That's double sided, leaving us with key tone which can then undergo another Greenert edition. So you okay, and then after an acid work up, uh, we get our original starting product, So just each 30 for us. Okay, so now for the 2nd 1 let's do the same analysis. Let's try to find the two groups that are the same. Uh, and it would be this one in this one. So those were our Grenier free agents. So we most likely started with this where this is this and this is yes. And that would be either to equivalents or in excess. Once again, let's do the same thing. Nope, Sorry. We need to equivalents or excess of our green. Your region, which is the other Peace is the blue piece. I m g. We are okay. And on to our final, um, problem Been part of the problem. We have this and what I see is two identical ethyl groups. So it must have been in, ah, Ethane based vineyard. So our original must have looked Our original greenery agent must have looked something like this. That is one carpet to carbon three carbon for carbon 512345 Okay, where this It's this and this is this Okay? And now we just need to add darker in your region. So that would be the ethyl groups. Oh, and we need either to equivalents of this were it has to be an access. Okay,

Thank you. List. He said so. Three reasons. One Carbonell component on the Greg. No relation to prepare two gumbos. What is species? It's fine. See? See, Exclusively s came on, Professor. See? Exclusive. Yeah, She Excuse me. Excuse me. Excuse. Seriously. Okay. On toys socially are gone. No, we can prepare this. Let's go. Yeah, my introduction. Oh, yeah. This blue this movie allow this on respective eagles so we can get this wrong. Yeah. You. Yeah. Yeah. This dope company. Okay, right. MD via Yes. Yeah, all they can get just from this veto. Okay, you know? Yes. You died in Syria. Mhm or the third off. Give face the bottom one. C 6 12 Libya reacting with See Evil. Uh huh. So these are the Haitians off the aliens. Similarly, the second one. Okay, C c at face ch two 123 Governments Onda for X mhm. Yep. That intense or Wallace breaking here. The, uh is breaking here or that That gives the same hole. The good option is, uh, since we have do it'll look to be introduced. We can do this, Foreign Minister, and you see how it works out. So the first one, then he Yes mg bia Yeah, The second option is he don't? Yes, he died. MTB are Yeah. 12 Yeah. You know, the story is so warming is still here. Will it? We can have. Yes, please. He hates to C two feed everyone for old csd Andi way Take two modes off detail in Devia. Okay, When the first more yards the associate reviews forming a Tito on. And when the second world reacts the second, it'll look better test 20 number.

Until for the coaching here. Until for part A, we have a me too. See all acetone. This is a certain and mhm m e m g c l Answer for a party. Answer for Barbie is edge to Siegel. Formally high maternal weekends here. Simplest Ellie Height and C s three CS two Oh, small five M g c l Answer for part C Beauty, anal and m e M G C l are eternal as Italy height and yeah, yeah, C H toy C H two all to m d C. L.

You can access this tertiary alcohol starting from Master, if you notice we have two. The same carbon subsist ruins that indicates is coming from the nuclear file. Which means the leftover Adams must have been from the original Lester. Of course, the Alcock side of Thie Esther is not seen because it leaves. So this really could be any types of carbon if we react. This s there. The three equivalence this cycle Excell Quran yeard. Well, access this product. Of course. The first edition will get you to the key town. The second additional gate to the alcohol. Second question has three pro pool groups. So of course, two of them have to come from the nuclear file, while one has to be from the original. Esther. So you can have this Esther say again. This part does not matter with three. He's going to of these purple opinions. I don't see any of these will access this tincture alcohol. Lastly, we have this alcohol so two meth will suppositions at this point. Those are Corinthians. Then the leftover portion is going to come from. Yes, there. So it could have something like this. You're acting with two baffle Corinthians. Really careful. M a h e. We are together. These will react to get you to your tertiary alcohol.


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