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CC(CHsiew structureHzoedit structurWhat reagent is neede wbere tbe "3" located?AciddaseurrPL IcftCheck my workNext pantPrevof 30NextMacBook Rro...

Question

CC(CHsiew structureHzoedit structurWhat reagent is neede wbere tbe "3" located?AciddaseurrPL IcftCheck my workNext pantPrevof 30NextMacBook Rro

CC(CHs iew structure Hzo edit structur What reagent is neede wbere tbe "3" located? Acid dase urrPL Icft Check my work Next pant Prev of 30 Next MacBook Rro



Answers

Draw the structure corresponding to each name.
a. 3,3-dimethylpentanoic acid
b. 4-chloro-3-phenylheptanoic acid
c. ($2R$)-2-chloropropanoic acid
d. $\beta.\beta$-dichloropropionic acid
e. $m$-hydroxybenzoic acid
f. $o$-chlorobenzoic acid
g. potassium acetate
h. sodium $\alpha$-bromobutyrate
i. 2,2-dichloropentanedioic acid
j. 4-isopropyl-2-methyloctanedioic acid

All right. So we are going to be, um, methyl eating eight species here. And, um, they're asked to predict the major model collision products you would expect to obtain from the reaction with coral, methane and aluminum chloride. So we're gonna go in order here. I'm gonna be giving some commentary as we go, because I don't necessarily think that this question is very well worded. Um, only because of some exceptions, you know about Friedel crafts that I think are being ignored here. Um, but so we're going to assume that all of these reactions happen. We're just going to go solely based off directing effects, right? So they want the major products. We're gonna give them major product. So let's start with the rumination products. Right? So, bro mean is an Ortho Parra director, although deactivating. And you may remember that deactivated rings are not going to undergo Friedel crafts. But, um, he slightly deactivated rings. The the have originated rings are okay. Um, but anything less deactivated than that tends to not undergo Friedel crafts. Also remember that Friedel crafts has a tendency to Polly substitute. So because the question said we're gonna have a mono Al Qaeda products. We're going to ignore that as well. Um, so we're gonna probably get a mixture of or foe and para, um, bro Motel, you in here? Probably favoring the Paris substitue int. The para substitution just from the roaming. Being a pretty large Adam, it's gonna, um, disfavor the Ortho positions due to some Starik interaction there. Um, so I know from from the textbook said that an Elin's tends to not react by Friedel crafts because there's ah amino group that is able to undergo pronation. Um, and that's true, but it's But there's also another reason, which is that the nitrogen tends to binds metals. Right? So Adams with loan payers will form coordination. You don't know about this yet. Maybe. But they'll form coordination the coordinate to the metal, which will inhibit the aluminum to be at an activated to be available to activate the the core. Oh, um, the Alka chloride four Friedel crafts to make the car more cattle on. So, um, fellows are also less active in that regard. But, um, the amino groups being stronger bases there, going to inhibit the aluminum's. That's why the textbook says, um, you can't deactivate of rings and amino compounds do not undergo Friedel crafts, but we're gonna pretend that this is fine for knowledge are tend to be okay, but I think the yields air just pretty low of these compounds. But we're going to ignore all of that, right? So anyway, um, the, um so you have to Ortho and para, um, directing groups. So, um, the effects of the meth Oxy star the effects of the final are probably going toe over, ride the effects of the bro me because it's a stronger activator. Um, so you have a tendency to want to put that at either of these or fill positions to the meth, Oxy or parents? Sorry that meth Oxy the final or parents of the fennel on being that bromate is an oracle. Parra director. I would imagine you're going to get some contributions, so I'm going to say they were gonna be two major products here. Um, probably the, um, you probably get some mixture, so you'll get a method group there, but you'll also form this compounds. Um, the sox seats are meta bro mean And that Ortho, um, but it makes some room here. Gonna movie over, and I'll move f over. Um, because you're probably also gonna get ah, this one. Right? So there's to Ortho positions. Probably disfavor. Is that one? Because you're shoving a method group that's relatively hysterically encumbering to the Ortho positions right between those two substantial in. So you're probably not gonna You might not want to draw this one, but it's still gonna be It's still directed there by both of the groups on the ring. Um, so you can't You can't discount it. Um, this is I would say this generally doesn't go Friedel crafts calculation because it is an amino group which the the textbook did say, um, tends to have a hard time undergoing Friedel crafts. But we're gonna listen to the question and say, Ah, what what products would I expect here? I wouldn't have felt any products. Um, but if it were going to be, um, react, it's gonna be, um, Ortho o para directed by the amino group. Um, but the power of positions are taken up by the chloride, so I'm gonna draw to products here. Um, really, it's one product because of symmetry, but, um, it's probably gonna go or so to the amino group, and then you could put it on the other side. But it's the same compound if you just rotate. Um, you'll have that position. You have that, um, and the other position as well. I'm not gonna put I'm not going to say the metal three Ortho position of the chlorine zehr gonna be favored at all. Because the the amino group is so much more activating that McCaughrean is deactivating. It's a much stronger director. So also, half the major product. Um, we have a try substantive ring here. Right? So you have the nitro group, Um, that wants to put this meta, but you have both of the Koreans that want to put it or foe to the Koreans And maybe para, um, which is the same position here. So because the nitro group, um, both of the chlorine zehr directing it to this position. Um, I'll say the major product is probably going to be between the corinne's, even though that might be relatively hysterically encumbering. Um, why can't There we go. So I'll put it right there. You might also see some, um, you might see some ah, or photo. One chlorine parroted the other still meta to the metro group. So I'll include that in my answer as well. You have a similar situation here with, um, this dyke or ofan ole. Um, you have the Ortho. Um, you want to follow the electron ICS of the of the final group. So it's gonna want to put this or throat to the final. Um, even though it's metta to both of the chlorine is a stronger director. So that's most likely going to be a major product here. Pretend there's an h pretend I have enough room to write my age. Um, sure, method was going to go there. Korean chlorine. Um and then it's gonna want to put it para to the, um the, uh, hydroxy over of the final group. But it's there's already a chlorine there, so also have the sole major product. Um, and then you have this bins all the hide, um, this bins, OIC acid, which I'm going to say is not going to undergo Friedel crafts calculation normally, because it's is deactivated ring. But for the sake of the question, so I'm gonna say no products, but if it were gonna be a product is going to go meta because those Carbonell groups are metta directors. So put the metal group there. You've No, I really doubt this is gonna happen. It's to deactivated. Uh, just two left. Um, also same with this. It is a deactivated. Bring actual. Check something real quick. Um, I would say even that Metro compounds probably isn't going to react by Friedel crafts because you have three deactivating groups. So, um, but if it were going to react, that's probably where it would go. Right. So, um, you have this. So you have this metal so far. So phonic acid, which, honestly, was probably not gonna undergo any type of, um, any type of methylation here. But if it was the meta directing strong the activation from that self cellophane, I could never say this. The so phonic acid group is gonna want to put this meta, which is also orthe oh to this Ortho directing methyl group. Um, but again, it's to deactivate of it ring, in my opinion. So, um, and then finally, you have this die Brill Motel. You in, Um, which is probably going to, um, they're all or fill power directors. So but it's probably gonna follow the methyl group being the stronger or full power director. So it's my most likely going to make these two compounds, Um, so you'll have another method group that is, or throw to the first method group, um, and that you'll have a compounds that is, um, PARA to that method group so you'll make a Diab Romo's Islay in in a way, right? So the question is, predict the major products. Even though I answered all the questions, I would probably say that, um, this Antolin probably wouldn't react because the amino group is going toe not be compatible with the aluminum chloride. That's something that was talked about in your textbook. I would say this parte de is probably to deactivated to react. Definitely. F is to deactivated to react, Um, and G is to deactivated to react, but I still in through the still drew the answer. If it were an activated suffering, Um what? Where with the substitutes guide that methyl group during the calculation reaction

Solving problem. 19 of chapter five grow the corresponding structure corresponding to the following names. So let's start from the 1st 1 The name is three. Matthieu. Want to benzene? No mine. So we see there is a benzene. So we started throwing a benzene ring. Then we know that in position one and two, we have to because we have this week's D. Um, I managed to So we have a position. Want less like this? One were manage to And we have another off the same group in position Toe. So we're gonna number, um, the carbon off the benzene ring in this way. One, 2345 and six. So one in tomb are already occupied. But the dia mine in position three, we have a metal. So we are in position. Three a metal. Okay, then we're orto Ah, my no benzoate Kosit. Okay, Okay, so we start throwing a benzene, then we know that we have to substitute wills and they are in order position with respect to each other. So we have one of the sub statement is in Amman on group and the other one is the car bacilli kassid. So let's start putting the first substantively here. And it's to them, you know, And then in order position that means on the carbon next to the first carbon containing the modern group. We have the car book Silly Cassidy substitution. So see or or age. Okay, then we have metta Brahma field. We draw It depends in drink. So the name fennel means benzene ring with an alcoholic group. So with or age And then we have a second sub statement. That is a promo in a meta were expecto the wage. So meta position is this one, So want to entry matter And here we are a bro Ming. Sorry. Okay, then we air tune for six a nice throw funeral. Okay, Mr. Or our benzene ring again. We have a feeling. So it means we have an alcoholic broke on the benzene ring. So let's start with this one. And this one is gonna be carbon one. So they're gonna be 12345 and six. So now we know that in position to for in six we are nitro group three of them. And so we put them in position to and or tool in position for on off two in position six and oh, to

Mhm. Uh huh. Yeah. Structural. You can come over first one. I should be 28 and I attribute your theories. See, it's their ch mhm or a teacher. This will trigger. There are four comments second companies or his personal Mhm. It's Chinese. 123 Go fight! Hold Latino toe ch two 123 Food. So everyone is a new standing on the food Kabul di request which opened Keep doing so we have the key to group we and then they open game So the I swindle group this is he It's three 12 Okay, one c Similarly, on the visiting 12 1234 For me Next companies a criminal psycho heads, you know. Three me tight. Same law hex alone. So here is so it looks in on dreamy Taylor. Next combo. New sir or 24 Thinking Diane Want to To food, Right? Who loses? Thank you. Two and four. We have my own full blown long three help channel. Happy. An honest one. Do you helped in on? We have to keep him here When this war is no grandmother war Have no ill behavior. Come down from a capital. I behaved. Yes, and good break Very slow. Seven governments. He is three c h b. Did you grow up here? Yeah. Onder see exclusively, Exclusively is three and women here he the well lets me 63. Yes. Let's see. Big school can go on the series Common with six are six comments. 123456 So we help see it or hear? And then gamma is my favorite. A gamma to know minutes early on This problem? Yeah. Next companies too little Cyclops Dane Car body head to details se clumping gain God, my behavior. Yeah. Yeah. So these two entitled commonly received Expo andi to either use c two h wild when his godly the last is for middle five. Also So no, hardly full retail for you Also, it's scenario No heck. Salaries six Got way 23456 x in our. So we put this here to heal five also 12345 also is to do And for many days

Here. All right. For a Richards? Yeah. Di Matteo lacks Undermined. Yeah, yeah, Structure will, before this will be like this. Fine six in this compound parent chain is a vaccine containing six carbon atoms with amid group as a functional group now attached to metal group toe the nitrogen atom Does the structure a song as follows? Yeah, No, for the option b he who will be in this component. The parent chain is a vaccine containing six carbon atoms with Emma Group as a functional group. Now the artist, the two metal group at the third position on the structure Is this my for adoption? See, this is cyclo have seen car carbonell chloride this ring containing six carbon atoms and place the a girl group to the ring for the Action De and Propane Israel in this chain containing three carbon atoms with including Santa group Carbon atom, Natural means Cyanide Functional group and thus this is the structure for next see also the e, which is propane. Um I'd and here's the structure for this is and this gen containing three carbon atoms with the, um I'd group as a functional group and thus the structure it has Polo's for option F Sodium acetate heard. That structure of this is in this as you did iron and place the sodium iron nearer to the auction atom. And does the structure this song G. Ben zoning and I'd read Sure. Yeah, in Panasonic on I dread the compound is derivatives off guard was allocated so and I dried and place the penile groups and does the structure. So one for adoption edge, which is carbon atoms. Yeah, and this elect on its say click Esther and giving component is with role act on weather. Romanes, it contains five carbon atoms. Beta is elect on, let on. Okay, no. For the auction, I retail built any trail in this chain containing four carbon atom with the sign of group as a functional group Place the metal group at the third position and does the structure that's followed for the J Happy Mother. The J, which is cyclo plantain car was I like acid in this chain containing five carbon atoms and place and the car was a league group toe the ring and does the structure a song. Yeah, for the K hopes and oh, which is benzoyl chloride her The ring place in the a Kyle group to the ring and does the structure Yes, for


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