4

Coriplete this road map problem by giving the product reagent needed for each reactionKMnOaLinhNhOk8OHCHSCHz C-CI21...

Question

Coriplete this road map problem by giving the product reagent needed for each reactionKMnOaLinhNhOk8OHCHSCHz C-CI21

Coriplete this road map problem by giving the product reagent needed for each reaction KMnOa Linh NhOk 8 OH CHSCHz C-CI 2 1



Answers

Fill in the lettered reagents needed for each reaction.

This is the answer to Chapter 20. Problem number 47 fromthe Smith Organic chemistry Textbook. This problem asks us to draw the products of each of these reactions which involves a new organic metallic re agent. Okay, so we ate organic metallic reactions here. Okay, So So for the 1st 1 we have Grenier free agent, and we're reacting it with carbon dioxide, followed by, um, some acid for the work up. Ah, and so this is going to result in, um, the carb oxalic acid. So remember when we react Ah, grin. You agree, agent, With carbon dioxide, we end up with a carb oxalic acid instead of like, an alcohol like we typically get. Um, when we use just analogy. Hideaki Ito. So we have, um basically just replaced our MGB are with the c 00 h. So we have the car back sell gas in there. Okay, so that's a B is a more typical grin. Your reaction. So we have Ethel Griner agree, Agent um and we're reacting it with this This bring system this by cycle. Um, and there's a key tone on the right ring. And so, um, the reaction's going to occur at that key tone carbon. And so we will add our Ethel group from the Griner Free agent. Ah, and our key tone will end up as an alcohol. Okay, so there we go. That's B for see? Ah, we're reacting. Um, and ask chloride with excess green. You're free agent followed by water work up on. And so here, what we're gonna end up with, um, is a central carbon on. And so we started with one federal ring. Ah, and our green Your dory agent is ah, fennel Grenier on. And so we actually end up with three federal rings on this central carbon. Ah, and then also Anelka hole. Okay, um, for D. We're reacting in Esther with excess greener, every agent on water work up. Um, and so what we're gonna get here eyes double addition of the greenery agents. It's a metal grin yeard on. And so we end up with, um, our federal ring fromthe starting material. So there is that. Ah, and then here is our carbon. That was, um, the Esther Carbon. And so it's going to have an alcohol on it now. Ah, and we will have the two method groups that added So one method group and a second. Okay, so moving on to the next page eso for e were reacting just ah Green. You agree? Agent with formaldehyde. Ah. And so the result of that reaction is going to be, um, just the addition of one more carbon to this chain with an alcohol on it. And so we have five carbons to start. Your product will have 456 carbons on the alcohol. So one hexen all is our product. Okay, Um, so then for F, I were using ah, copper lithium re agent. So it's the metal organo. Cooperate. Um, and s o. The reaction here is going to take place at the double bond. Um, so not the key tone key tones gonna be infected. Um, and basically, we just end up adding, ah, metal unit to this change. So it's an eight carbon chain to start 2345678 nine. Now it is a nine carbon chain. The addition of that method group took place at the the AL Keen on. And so there is our key tones still intact. And so that's f for G. G. Is just another typical grin. You agree, Agent s. So it's gonna take place at the key tone in this molecule. Nothing else about the molecule, including that Al Keen eyes going to be affected by the reaction with discrim yeard. So there's the out keen still intact. As I said, um, and then here's the rest of our molecule, so our key tone has been reduced to an alcohol. Um, and we've added a method group here. Um, move that down a little bit, just so that it's easy to see. Here we go. Okay. Yeah. So we've added, Ah, I've added a meth. A group on our key tone is now an alcohol. Okay. And so that's g. And so lastly, um, we'll take a look at h S o h your organo cooper. It that we have here is gonna act is nuclear file and open this up oxide. Um, and following the rules for a pox side opening, it's going to attack at the less substituted carbon in the epoxy side. Um and so we will end up with this of hoops. So here's our C six h five unaffected by the reaction. Okay, um, and so again. The the cover lithium is gonna act as, ah, nuclear file an attack at this carbon. And so what we end up with is an alcohol here. Um, and there's our second carbon from the pox side on then. Since it was, ah, metal, copper, lithium or metal Cooperate, uh, that we were using. Um, there is our added metal group, okay? And so, um, that's the product for h. Ah. And that's the answer here. Uh, the only you know, there's no secret to these. You just need to know how these organic metallic re agents react under all of these conditions. Ah, and that's the answer to Chapter 20 problems of a 47.

This question covers predicting the product of and I have a reaction between methyl bromide and each of the following equal files in a substitution reaction. We're gonna go ahead and just go down the line here. Um after the problems inside the book of the chapter, we should be relatively straightforward. Um So in this reaction where you're going to see that we're going to have our arrow pushing. Looks something like this and we're going to form It's a methanol great one here. Look plus Yeah minus. Yeah. In our second example we're going to see similar arrow pushing. We're going to form this mess. Olympia. Yeah. Yeah. Mhm. Mhm. And remind this next example. We're going to have some well impairs that again, will attack the carpet over here and this will form Okay, file compound here. Plus our romy bromide ion. Similar reaction here. Mhm. Mhm Mhm. He would probably see actually, yeah. Have an exodus. Mhm Plus HPR Yeah. Mhm. Yeah, like this. And we'll definitely see that in our next example that we are forming. How do I get sorry? Yeah. Not for 100 brake acid. You're forming a file neutral style with the bromide ion. Yes. In our next example again we're going to see Yeah. A similar reaction that looks like this and we're going to form a knife. Di ethyl ether. Yeah. Mhm. And in this the last example we're going to see something like this. We know that hydrochloric acid is Yeah. Yeah. Very acidic. And that means our basic So we're going to expect a quantity very mean. Yeah, bromide salt. Yeah. As our contrary substituted. But this second the secondary amine that's been doubly protected, forming assault. This. Mhm.

Actually. Great. So problem 30. We're starting out with Pass it on using L. D. A. As a good base are going to form this in a late should actually be single bond here The one there Next to react thing with this all behind is this Alfa Carbon Galactus nuclear file to open this up. Well then, generate Deal with him on this position. Finally, after water, we're going to prison. Eight. Generate your beta hydroxy key town for be We're starting with an us there using this good bass again. Deeper. It's innate this Alfa position. Well then generate this annoyed she'll then react with a little fence. Here I'll go hide again thiss nuclear files going to look for a son Electric Felix center And that is just a this AL behind position. After this attacks, you will open up. It will generate back our Esther. Her new bond we formed it will have the rest of the molecule drawn like this. Of course. Finally, after we have water, will protein eight Carl Cox side to generate thie beta hydroxy Esther has the final product


Similar Solved Questions

5 answers
Find the logarithm log1(1, 000, 000)PreviewGet help: Video
Find the logarithm log1(1, 000, 000) Preview Get help: Video...
5 answers
Aleinjie) pH of 120 M 2 (Kb 5.6x10-10)
aleinjie) pH of 120 M 2 (Kb 5.6x10-10)...
5 answers
QUESTION 13:Find the exact value of the integral:(3 _ 2x) dxVl +edx
QUESTION 13: Find the exact value of the integral: (3 _ 2x) dx Vl +e dx...
5 answers
Cnpsto %o Ers: torvetvzd #" (ito foLox ns Fcztioxa. Bicizlly %F*r' Erxxza. {0} {c; 4 AJ '4;(2;DashbearoCalendarTo DoNotificationsInbox
Cnpsto %o Ers: torvetvzd #" (ito foLox ns Fcztioxa. Bicizlly %F*r' Erxxza. {0} {c; 4 AJ '4; (2; Dashbearo Calendar To Do Notifications Inbox...
5 answers
21 2 the sin(tt) , et ) line integral for <t<1. dr where 3 (6 '2x sin(y) 22 cos(y) , 1) and is given by
21 2 the sin(tt) , et ) line integral for <t<1. dr where 3 (6 '2x sin(y) 22 cos(y) , 1) and is given by...
4 answers
Questionl9What is the correct name of this molecule? CH; CH; CH;CCH,CCH; CH; CH;
Questionl9 What is the correct name of this molecule? CH; CH; CH;CCH,CCH; CH; CH;...
5 answers
Rataining Mme? hour; 21 Imnutes, 37 second:Question Complation Stafus:ZG AGLC]nJlMoving anolner quesilon Quve Ihls EspongeQuestion 1JOue o 1J4'25Two idcntical sinusoidal Fee Warci suinultancously" Icsent satt1€ directon along tlt $unz sttin< warc Each #Jic #hat I9 the phase diffctence between tc ti0 uares?pcintzurnpM udc ofye Efth- Enpitudr &ftl0AEL0Cueanan #Jer79"acer
Rataining Mme? hour; 21 Imnutes, 37 second: Question Complation Stafus: ZG AGLC] nJl Moving anolner quesilon Quve Ihls Esponge Question 1J Oue o 1J4'25 Two idcntical sinusoidal Fee Warci suinultancously" Icsent satt1€ directon along tlt $unz sttin< warc Each #Jic #hat I9 the phase...
5 answers
4x6 + 3+_ +42x4 (10 points) Given f(x) = find r+r 30r- any horizontal asymptotes of f (x) algebraically using the calculus techniques discussed in class (no shortcuts!) . If Lhere are nO horizontal asymptotes, state s0 AND describe any infinite behavior using limit notation.the x-values of any holes of f (x) algebraically. Remember to show your work.
4x6 + 3+_ +42x4 (10 points) Given f(x) = find r+r 30r- any horizontal asymptotes of f (x) algebraically using the calculus techniques discussed in class (no shortcuts!) . If Lhere are nO horizontal asymptotes, state s0 AND describe any infinite behavior using limit notation. the x-values of any hole...
1 answers
Rights Gates Window Mfg. is considering a rights offer. The company has determined that the ex-rights price would be $\$ 45 .$ The current price is $\$ 48$ per share, and there are four million shares outstanding. The rights offer would raise a total of $\$ 60$ million. What is the subscription price?
Rights Gates Window Mfg. is considering a rights offer. The company has determined that the ex-rights price would be $\$ 45 .$ The current price is $\$ 48$ per share, and there are four million shares outstanding. The rights offer would raise a total of $\$ 60$ million. What is the subscription pric...
5 answers
A mutation in the promoter region of a gene would most likely cause change in the amino acid sequence of the protein that is produced change in how well RNA polymerase binds to the promoter region more than one of the abovechange in how much of a particular polypeptide is produced no change in the organism
A mutation in the promoter region of a gene would most likely cause change in the amino acid sequence of the protein that is produced change in how well RNA polymerase binds to the promoter region more than one of the above change in how much of a particular polypeptide is produced no change in the ...
1 answers
Find the derivative of each function. Verify some of your results by calculator. As usual, the letters $a, b, c, \ldots$ represent constants. Derivative of a Constant. $$y=8$$
Find the derivative of each function. Verify some of your results by calculator. As usual, the letters $a, b, c, \ldots$ represent constants. Derivative of a Constant. $$y=8$$...
1 answers
Solve the given problems. A person is working out on a treadmill inclined at $12 \%$ (the slope of the treadmill expressed in percent). What is the angle between the treadmill and the horizontal?
Solve the given problems. A person is working out on a treadmill inclined at $12 \%$ (the slope of the treadmill expressed in percent). What is the angle between the treadmill and the horizontal?...
5 answers
Find the center of mass of a thin triangular plate bounded by the y-axis and the lines y =X andy=2-x if 8 = 8x+ 8y+4.The plate's center of mass is located at 16, 32 (Simplify your answer: Type an ordered pair: Use integers or fractions for any numbers in the expression )
Find the center of mass of a thin triangular plate bounded by the y-axis and the lines y =X andy=2-x if 8 = 8x+ 8y+4. The plate's center of mass is located at 16, 32 (Simplify your answer: Type an ordered pair: Use integers or fractions for any numbers in the expression )...
5 answers
PointsSave AlFind the equation of the line that is perpendicular to y-3x-7 and that goes through the point (-1,2). Give the answer in y-mxtb form_ y-(1/3)x (5/3) b.y-(-1/3)x (5/3) Y-3x+5 d.y--3x+5
points Save Al Find the equation of the line that is perpendicular to y-3x-7 and that goes through the point (-1,2). Give the answer in y-mxtb form_ y-(1/3)x (5/3) b.y-(-1/3)x (5/3) Y-3x+5 d.y--3x+5...
4 answers
One reaction of the Glycolytic Give the following Pachway involres both oxidation and phosphorylation inforation for this reaction: 6) The name and chemical structure ofthe substrate The name and chemical structure of the product: The name of the enzyme Any cofactors required during the reaction
One reaction of the Glycolytic Give the following Pachway involres both oxidation and phosphorylation inforation for this reaction: 6) The name and chemical structure ofthe substrate The name and chemical structure of the product: The name of the enzyme Any cofactors required during the reaction...
5 answers
Q1: (5 Pnts.)a ) Show that Zn Jn(x) = xUn-1(x) + Jn+i(x))b ) Using the Rodrigues formula Pn(x) D" ((x2 1)") find Po(x),P(x), Pz(x) 2nn! Then rewrite the function f (x) = 3x2 Sx + Zin terms of Legendre polynomials Reduce the integral f xJz(x) dx t0 integration in terms of Jo(x)
Q1: (5 Pnts.) a ) Show that Zn Jn(x) = xUn-1(x) + Jn+i(x)) b ) Using the Rodrigues formula Pn(x) D" ((x2 1)") find Po(x),P(x), Pz(x) 2nn! Then rewrite the function f (x) = 3x2 Sx + Zin terms of Legendre polynomials Reduce the integral f xJz(x) dx t0 integration in terms of Jo(x)...
5 answers
Detetmine 'nether Ine sampling Metnod descncer Delo ' 3002305sound Ol Is rlatyedstnvey 0/ 618 sublectseach was asked how onen nutttosic0r ae readbook The survey subtects were Intemet users wrho espondedctesuon thaiwa= costedChoox the correc #nswet belowlawed cecausenai stalislically sign ficant hds llawed bucause Ie CnnaltMIs Ilawved 6ucaus0Younny Mitdont TmollappeaisRoninardfcannfrne Gae ara not blasadanmay
Detetmine 'nether Ine sampling Metnod descncer Delo ' 3002305 sound Ol Is rlatyed stnvey 0/ 618 sublectseach was asked how onen nutttosic 0r ae read book The survey subtects were Intemet users wrho esponded ctesuon thaiwa= costed Choox the correc #nswet below lawed cecause nai stalislicall...
5 answers
Molet epectnlling Useyan Itomic , 1 Emission Spectra comnplcte tre L 1 1 1 Mhbtanat 1nolm (Ipts) Gcieal obsennllon1DVI?
Molet epectnlling Useyan Itomic , 1 Emission Spectra comnplcte tre L 1 1 1 Mhbtanat 1 nolm (Ipts) Gcieal obsennllon 1 DVI?...

-- 0.019485--