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Instructions: For cach of the following reactions, draw the mechanism two times: Make sure to Redraw reactants b) Include lone pairs on all elements Include flow of...

Question

Instructions: For cach of the following reactions, draw the mechanism two times: Make sure to Redraw reactants b) Include lone pairs on all elements Include flow of electrons d) Include Stereochemistry if appropriate e) Include ALL minor speciesEZ dehydrohalogenation (Elimination of HX)NaOCH;CH;CHzCHCH;HSCHC CHCH3CH;OH

Instructions: For cach of the following reactions, draw the mechanism two times: Make sure to Redraw reactants b) Include lone pairs on all elements Include flow of electrons d) Include Stereochemistry if appropriate e) Include ALL minor species EZ dehydrohalogenation (Elimination of HX) NaOCH; CH;CHzCHCH; HSCHC CHCH3 CH;OH



Answers

a. Draw the product of each of the following reactions: b. Give two sets of reactants (each set including an alkyl halide and a nucleophile) that could be used to synthesize the following alkyne:
$$\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CCH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}$$ c. Give two sets of reactants (each set including an alkyl halide and a nucleophile) that could be used to synthesize the following ether:

This question asked for the products of each of these reactions, including steroid chemistry and when you're only drawing substitution products here. So starting with the letter A. We have a secondary leaving group and a good nuclear files. This will be an S end to reaction, which means will only have one product send two reactions. Give us complete inversion of stereo chemistry. So we'll put the meth oxy on a dash. And the bombing was on a wedge here, um, and the hydrogen be on a wedge now. So there's our single product for part A For part B, we have are three remote, three metal obtain and methanol. So now we have a tertiary leaving group and weak nuclear files. This will be SN one for substitution. So we'll get to an answer. Humors here because if we're doing s and one, it goes through a car broke out. I am so you can end up with the nuclear violent either side. So we'll have one where it's on the same side of the bro. Mean was on that will look like this and we'll have one where it's on the opposite side like this serves air to Syria. Ice murders for part B for part C. This is also in sn one reactions because we have a primary buttons Ilic Carbon cat eye in there at a weak nuclear file. There is no stereo chemistry here because we have two hydrogen on that carbon, so it's not a stereo center. So we'll just get one product that looks like this was replaced the chlorine with the Foxy Group and then for D. This is also going to be in sn one because we have a primary Elik, carbon cat eye in there and a weak nuclear file. But we also have to take into account that because we have a primary a Lilic, um, nuclear. Pharrell here, this is our right. This is going to be our car broke a tie in, and this can also resonate, um, and put the car broke out I and over here, which in this case is the exact same thing. So we still are only going to get one product from this reaction and that will look like this again. This is not a story of center right here because there's two hydrogen for part E. Again, we'll have a primary a Lilic. Ah, leaving group. But this is a good nuclear for a house of This will be in sn two. Um, and so will only get one product here, which will look like this. Uh, And again, this is not a serious center, because there's two hydrogen is there. And then for part F, we have again this primary Elik, carbo cat ion and a weak nuclear viral. So this will be SN one. Um, So if we take a look at our carbo cat I in here, it looks like this. If we resonate this, we actually do get another product. Um, like this. So our product from that first carbon cut line will look like this and from the second will look like this. Um, and this one appear doesn't have any serious chemistry because this is not a stereos under it has to hide regions on it. But this is a stereo center, so we can either have this on a wedge or on a dash. So we have a total of three products for a party

So in this problem, were asked to consider the reaction of CIS to beauty mean with water HBR and C L two. So here I've already drawn the structural formula for Cece Tube you teen, and we're going to go one by one through these reactions. So on this first reaction, we know that we're gonna add a h and N O H across our double bond. So here you have a keep this and now we're gonna add a each and in O h across here, we're going to do the same with each We are. So instead of an agent and ohh you add in H and a br cross all right, and then we're going continue on to the next one. So now again in seven h and a BR or an agent Oh, each were adding a C l in the c l. And that's it

For some new C. Six. That's five CS. Won't say yes we are. You see six at 5 Ch reacting with Then we will get 36 X five C. H. B. I see it's rubio like now it is reacting with any image too. Any excuse the very strongest so the strongest can eliminate both growing go both of you. There are two more of an area little girls eliminate. And then we will get right. This sentence is reacting the c. s. three. I further not seriously. Here we can hear we use only two more of an NS2. So one mole is also remaining. So NH two miners will abstract this acidic hydrogen night. So this acidic hydrogen is reacting with the CS three doing back here and I will get eliminated. And then we are getting this temple. Okay so it is not the thanks. And now for them this. So first we used to and so forth. And that? S possible reaction here is the watch. No, that's too as a food all they do and now and this is the compound. First we use benefits to the food. Then we will get concentrate. That's good. That's good. I hope you are getting cancer. Okay.

Hi, everyone. So, in order to tackle this question Okay, we'll see in first 19th. Yeah. So this would be for such to TV. Is there? Our substrate is their age plus skin minus. So this undergo a cento mechanism in present self acetone as a sole went mitigated ground. No, not builds. Excuse us three. Yeah, it's man candidates. Sigh made. What is mechanism? Yeah, mechanism of this reaction. Oh, so in orderto see, the mechanism will force draw the sub strict. Hey, so in this case, you know, reaction is a cento So nuclear fanatics from the side opposing toe grow mean So what you get is in other words, a backside attack of the nuclear fire takes place by excited accompanied Blute fin takes place so it undergo the same to reaction They excite attack a bank off CN minus to reach roaming departs, roaming be pops. The arts but blow mean is not attached to the Kyrill center domain. It is not attached to the Tyrol center. My parents to the viral center, Cardinals center. Therefore, stereo kmsp Uh huh is not taken into account is not bacon into account. Oh, than being mhm. So you can go like this, That is well, I think Lane indicates Brahman is coming towards the absurd. What are coming about the plane? Less loneliness. See? Extreme. Uh, this also undergo ascend toe making itself okay. So in this case, since the prominence attached to the corral carbon, there is an inversion of configuration takes place. So now will rate the mechanism. No, but it's mechanism. Mexican mechanism is step by step description of any chemical reaction. So, no, in this case, this liberal me then this sense Hey, division. So we talk, Cillian, you too. Thanks. On the backside. Mhm to reach Rome. India bars eso What That is? Yeah, so they percent emerging off configuration takes place. Takes place. You do back Syratech in case also, that is a way out of Magnus. So yes, and do my can is, um my kidney something since bro mean is that Kyrill center Kyrill carbon 100% inversion off configuration takes place. Takes place. Do you look like Syratech? Yeah, a tank off. Oh, minus. Yes. That really moto the See? Okay. See, part of the question that kids here is Yeah, Then C h two heads to CS three love? Yes. Three or age, right? This proceed if I a s n one mechanism. So yeah, l a gate tubular. Yeah. One is with a retention in configuration on one with inversion in computation. So this is people sent. You can say, since it involved both retention and now inversion, we can label it as a civilization. So I have a civilization takes place All this mechanism making yourself so you know, be our land. C h two c h two. She is so severe. Become a bone, becomes a polar and send one mechanism. Andi, Therefore, Brahman first gets departed and still gate a Carboni in Miami playing this Now you know there are two possibilities. My pills. I don't need clear file. Yes, to me or h it. Also in writing this Yes. Off page? No, you know, nuclear fine. In this case, you can say attack from the same site to each blooming departs. So it is a French side attack are it? May attack from the sale opposite to the Roman item. So you can say this is back. Syratech, make Sarah Tank. Yeah. So once it attacked from the French side, what do you get delegate are interesting. Positive charge. And this C H two said stuff ch three nine. This erosion loses it. That is, it forms ageless. So Okay. Oh, ch three men. Yeah. C h two c h two ch three No, in back side A deck that this So this is actually a retention in configuration. A retention in configuration Nos my back Saturday. Okay, you know. Okay, so this also yesterday approaches from the back side should not be a positive chance. So this proton undergo loss on real gate. Okay, Inversion of configuration in watership off compilation and therefore s someone mechanism. This reaction follows. And one mechanism at banks off methanol takes place from front and back side bank side. And this I see magician doctor takes place. Then we will go for a D reaction. Yeah. Okay, so no, in our edge, then. See? So we do a child, man, it is I. Then this is no ch three less CS three ch this creation process via and sent to making yourself. So you get 20% in virginal corporation like these secrets five than edge then ch three. They say it's all seasonable. Von does Yes. Yeah. Now, let us study making is, um, making some of the reaction so possible will draw the substrate there. These carbon, then C two h file, then? Yes, it's what he's saying. Ch three I So you know C S d c h. She has three, then syllable Wando. Oh, age. So, you know, wintertime from back side to which during the pulse goods are indeed parts. So you gained. See bridge for you bank yet? Yeah. Search tree. Oh, Seasonable Wando ch three. Yeah. So this undergo deeper donation and still Gates, you could not do it. Nay percent in original compilation CS three oh, school CS, three 100% in Russian. So does reaction process. So I ascend to mechanism back. Sarah, take off. Yeah, Nuclear file takes place, resulting in 100% inversion of computers on a few duration. Then we'll move. Waas The e e part. There is, uh, esto fund will draw this NPR, right? Yes. So this under will I send to make any ism on and again, huh? Less seed rich for you Arrange. So yeah. In this case, prominence attached. Oh, a viral carbon. And that's why in original contribution takes place. So 100% in words. Now, let us see the mechanism. That is how it takes place. Mechanism? No US PR bank spills. Yeah. Okay. Okay. Plus, you can say C two h U Oh, edge. So this would like bank from this side. It's become in regal. I So what we get is yeah. This than Yeah. Okay. Exact Opposite configuration brigade. The to the ends with Come to this side. What do you say? Oh, seemed to edge for you yet. Plus, so this undergo deep rooted nation. What? Yes. Mhm. Oh, see, Bridge fire. So I sent to reaction. Like anything back side attack, I think Doug and it was said in original computation takes place. Thanks. Place. The next one is yo, Seals, right, CS three less cst CS to wage. Okay, this also undergo I seem to make any ism. So, uh, in this case, uh, Tulio to take care. This is a dinos minus. So till directly from this, So go. Yeah, CS three. Then there is or Cito Ph for you. Yeah, that is 100% inversion takes place, So make any some make any something now, E no. This is. See end 90 s three and then you know this C S E C s to age. Attack takes place from back side. Mhm, Chief. So Oh, ch two ch three. Yeah, it's I had his day. He drew some. So these the general reporter nation for me. What? Yeah, yeah, or ch two c s three. So E therefore, I cento eight underwear cento mechanism resulting in 200% inversion in the mother ship off computation. Okay, Federation, do you do back serotype? They do backside. A death. Thank you.


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