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Propose an efficient synthesis for the following transformation: 4. . | n| ' Rfnon beulotso-D3e nG w4G Ean etnee N* ~aeianep notte .( ' 57 W 2 363 J0 ...

Question

Propose an efficient synthesis for the following transformation: 4. . | n| ' Rfnon beulotso-D3e nG w4G Ean etnee N* ~aeianep notte .( ' 57 W 2 363 J0 Gvid 3oot ?i Snimneha Fetteeeee 1 Knini I9vo ; . de S

Propose an efficient synthesis for the following transformation: 4. . | n| ' Rfnon beulotso-D3e nG w4G Ean etnee N* ~aeianep notte .( ' 57 W 2 363 J0 Gvid 3oot ?i Snimneha Fetteeeee 1 Knini I9vo ; . de S



Answers

Propose an efficient synthesis for each of the following transformations: (FIGURE CANT COPY)

Going on with the reactivity off Elkins and all kinds. So we have a few different examples to take a look at, so we'll jump straight into the first example that we have. So what we have is this starting material and then in the presence off P C I five, there are degrees south CIA. We found the following what we have ch three c c i to ch three. Let me have three equivalents of any NH two mineral oil and heat on what we form is an al kind. You have ch three C triple bond C H to have SP hybridized carbons associated with that triple bond. Next, what we have is ch three stage two c h be off to so again the same re agents of mineral oil Heat two equivalent of NH four plus we then generate our al kind against. We have C H three see triple bond C H without SP hybridized carbons while we're using all of those pill bottles. Now for our sad reaction, we have ch three c h v r c h two. We are using the same the agents that's have used all along to form or al kind, which is reminding ourselves or triple bond used with our SP hybridization. It's moving onto the final example. What we have is ch three c h double bond, C H two. Then we have the off to that gives us ch three c h p r ch to be off, have the addition off Burr mean We then have the same regents that we've used all along informing our al kind bond ch three c triple bond C H.

Look at another retro synthetic analysis. So we start off with our starting material than what we will do is make a synthetic cut will make a synthetic cut here. Now we can think about materials that we might want to use in order to generate our target molecule. Of course, with missile magnesium burn mind starting material, we will convert that to just forming containing confounded normal black backwards by introducing Mike Museum with 82 of So when we look at these synthesis, we have the one Brumer for hydroxy missile Cyclo heck scene We react that with ch 33 c s I c h 32 c l in my dissolved This is them reacted with magnesium in ether. To generate ongoing yard re agent, we then react this with our other starting material which is this material generate an intermediate on. Then what we will do is get rid of that silicon containing group by introducing beef or and plus F minus


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