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Draw the organic product(s) of the following reactionaqueousH2804NaCNYou do not have to consider stereochemistry: Draw one structure per sketcher Add additional ske...

Question

Draw the organic product(s) of the following reactionaqueousH2804NaCNYou do not have to consider stereochemistry: Draw one structure per sketcher Add additional sketchers using the drop down menu 1n the bottom right corner Separate multiple products using the sign from the drop-down menu

Draw the organic product(s) of the following reaction aqueousH2804 NaCN You do not have to consider stereochemistry: Draw one structure per sketcher Add additional sketchers using the drop down menu 1n the bottom right corner Separate multiple products using the sign from the drop-down menu



Answers

Draw the organic products in each of the following reactions.

This is the answer to Chapter 19. Problem number 33 Fromthe Smith Organic chemistry textbook. I mean in this problem were given four reactions and asked to draw the products of each reaction. Um, and so for a we have the oxidation of a primary alcohol using chromium trioxide, sulfuric acid and water. Um, and so the result of this oxidation is going to be a car box. It like acid. Okay. And that's a I so for be, um we have, um, a di substituted aromatic ring. Um, and both of the benzoate positions here have hydrogen sze on the on those carbons on. And so they are actually both going to be oxidized by Cam and 04 And so our product here for B I's going to be a dyke or box that, like acid one car back. So Gassid Ah, and then a second corps box selling gas. It eso both of those ben zealot positions can be oxidized in this reaction. So then, for see, I'm we're treating an al kind. Ah, with ozone followed by water. Um, and so since it is a terminal al kind, we're going to get, um, one carb oxalic acid. Uh, and one equivalent of co two. Um, And remember, if it wasn't a terminal al kind, we would get to carb oxalic acids. But since it is terminal, we do get that equivalent of co two. So then for D. D is just another oxidation of a primary alcohol. And so nothing about the rest of this molecule is going to change on, so c o h So there we go have Ah, carb oxalic acid there. Um and yeah, and so this is Ah, this is the answer here. Um, it's three oxidation tze and those analysis on Remember, the O's analysis of an al kind is gonna give us to carve oxalic acids or in this case, because it's a terminal al kind one car box so Gassid and one equivalent of carbon dioxide. Ah, and that's the answer to Chapter 19. Problem number 33

Hello, everyone. Today we're doing Chapter 23 Problem 52 and this from Master. Draw the products in each of these reaction. So let's look at a first way and we have some sort of cardinal group with an Alfa Hey light. And then we're adding some sort of regions that will promote elimination. So no lithium bromide, well associate insulation, lithium plus and BR minus and br Maya slacks is a nuclear file to cause an elimination reaction to occur when she'll pick up one of these protons making bond and then the cinnamon will break to form a new pie bond. So for a we could say that going to get an elimination product and when you make a bunk, you break upon that, Roman will fall off and we will fall. Anu lamination product in which you will form close both the e and is the ice immer. So care behind we drew the worst. We could also have Z with these two groups on the same side. So for B, we're adding heat. So what we know about heat is that they promote spontaneous dicker box relations off Alfa Ah car salt acid group. So if you see here like this is a carbon gas and so yeah, she's blow this up a little bit. Dennis, give her this and clothes for now. Now it's better. So now we see that this car looks like acid is actually Alfa to a cardinal group. So when you add heat, the lone productions and this oxygen will go to farm Seo to making buying makeup on your break about. So this bond's gonna break. Go to this carbon nucleus and pick up this proton to neutralize it. So for Beacon, say that uniform, a spontaneous deco box elation product using heat and on Lee for carpets of your another. Carlos lead acid here. But there's nothing Alfa to it to promote the spontaneous decoder box elation of things driving this reaction on this carbon so gas and is just happy to stay as is but here because it's Alfa to a cardinal group because is promoted to go through that contains Deka box elation to form two products and increase the entropy of the system. Four. So now you have products for B man, see what we have lost Rossia so in, actually visualize it's over. See we're starting with 123123 Concerning with this grouping raising ld you just strong basic deep rolling this out for proton and they were adding alcohol like lips. When at those two carbons off this the alpha position because we're forming a nuclear. Found these intellectual file, so haven't s into a nickel a flick attack. Add those two carbons here to form product. See now for deed, what we have is an Alfa Hell. I didn't were reacting with the strong nuclear files being this aiming group. So what can actually have is just a simple lesson to back side attack within version of sterile chemistry here. So for deer has have simple nuclear filic attack s into a nuclear Philip attack with immigration of steel chemistry. You have carbon ending those two carbons here. It's nicer things now. Three bombs maintain neutrality. Ms. Gillis, products for D. Now we have ld Inns again this anklet light, but now we have to offer positions that have two takes out the carbon. Remember, Ellie is big and bulky, so it's going to give us. There's gonna de pro Nate the least air 100 side. That's going to be the right side. So it's gonna give us the kinetic product so deep only this right side to make a carbon and which is very nuclear flick and reactive. And it's going to react to this electoral file to get two carbons at this. No. In addition at this Alfa position for E. So now we're gonna add those two carbons at that off the position for me now F We have some sort of acid catalyzed halogen ation and crying. So we'll add intelligence to the Alfa position, but only half a position that is available that doesn't already have four bonds. Nana hydrogen bonds is the right side. We have one hydrogen that can be removed two in replace the hygiene with Romi. So for F after Step one, we're in a halogen ation occurring at the Alpha position. And then we're adding seem regions and in determined that those regents are leaving group regions or society what we could call elimination region so we can have an elimination reaction occurring in which this proton here's gonna be deep pro nated by this bromide ion. We'll have deep pronation making by make upon breaking bonds you nicked from a new pipe on and make a bond break up on the Bowman will fall off two formed elimination product in F, which is now this product here. And I'm g you're adding his excessive hey, lies to his terminal carbon Alfa carbon here. And then we're using this in this's occurring in the base catalyzed manner. So But we can see that you have some sort of hallow form reaction occurring in which the three hydrogen zap this terminal position and be released for I replaced for Aydin's. And then we're gonna have hydraulic system occurring from using the space. So in seeing G after the items were added, we'll have three dimes. I was replacing the terminal carbon hydrogen and then we'll have the always coming for Wallace's at this electoral Philip Carbon to kick off this good leaving group. Now, this is all for G and I we're gonna have on fraud us being It's halal form being formed with an oxygen attached to basset. And I see eye for our C I c i three cage they're forming minus on DH c I three h r ch three on way are on h so on each. What we see is that we have the sign of group were deep but we have a strong, deep resonating Egypt. So h minus is not stable h minus or rather the h two we're going to pick up in acidic proton and there will be knows Alfred to sign, or groups just like Alfred to Carballo groups. These protons are acidic soaking deponent that make our ban on at the south position. And then well, we have a few carbons down is a good electoral fall, so we can have intra molecular cycle ization occurring to form this election to form our product here. And then we have 1234 a five member intra molecular ring being formed off the science group. No. So for each, we enjoyed a five member dring, the mu forms and then we're gonna have the science group. Now, I we have same conditions as in G. But now the only difference is this instead of a terminal carbon with intra molecular carbon. So there's only two protons. So after replaced these two protons of Brahmins, even if this always mind is worried to attack, there is no good leaving group because it's only has two Hill. I did not three like the sternal position, so we actually can go through High Jolla, CeCe and I. We can only add or replace off the tooth ease to hydrants for two Brahmins, and then that's that. That that's the completion of the reaction is nothing further that weaken do unlike when it's a terminal carbon when we're adding these religions. So when it's a terminal carbon mean go all the wayto hala form our formation. However, when it's an intra molecular Alfa Carbon, we can't form Hala forms because Teligent ation. So you're just gonna replace those two hydrogen ZX with two brooms? And that's with the completion of our reaction. And last but not least, you have. So your idea is so typically lighting is a leading group of here. It acts as a nuclear falcon's eye minus, so you can have a simple lesson to her backside attack with this electoral file. Another hail, I'd just gonna have, um, halogen replacement or changing identity of your halogen from chlorine tidying. That's a product for J.

Let's complete each of the following reactions by drawing the products a age three to ch. See it to C h c o h b r. This is gonna be reacting with, um, in each three, which is present in excess. And this would yield product ch 32 c h c h two c h c O minus NH four plus and H two and N h four and B R minus. There would be the products for a for be. We have ch three c Oh, and H c h c o e t c o e t. And this is going to react first within a o e t and second with see double Bond. Oh, ch three. Oh, ch two br and first product here would be ch three CEO. Yeah, right on. N h c c o o e T C 00 e T C h two This ring. Oh, see? Double Bond. Oh, ch three. Further reaction here. Um, on the addition of acid and heat thing, this would be three. And this would produce h two n c c o h, Yeah. Each c h two benzene ring. Yeah, O h I need you. There is our final product for C. I have one too. 34 in each. Double bond. Oh, double bond. Oh, this is going to react first with NH four c l and N a C N to produce one three. Well, 23 on H double bond. Oh, sweet H, C N and H two. And this would further react Number two with h 30 plus to yield and H two and H two h and C O h. Here's our final product. And lastly for D, we're going to have C H 30 c h o double bond. Oh, first reaction here. It's going to be with NH four C l and an A C N to produce C H three, go three see double bond. Oh, in h two c n and H And then our second reaction here with each three or plus will produce C H 30 see double bond. Oh, in h two each. C o h. And there is our final product. Um, one more for E. We have C h three c o N h C c o E T Yeah C o e t on h and this will first react with C l ch two ch two ch two c h two n h a c and this would produce C h three c o N h See? Yeah. C o e t c o e t ch two ch two ch two ch two n h a c And then upon a second reaction here yeah, with H 30 plus and heat. This will yield H two n c c o h h ch two ch two ch two c h two n h two And there is our final product.

Here. The ocean is brother orderly Produce food, Invitation. So in the first case, a similar statistic on and said I just region with a sit again. Hi, Jake. And then a cilice agility is Connecticut resolution. Where the presents off, kid Allah and saying, Silas So you're getting younger, uh, the specific good in Schumer. So in the first case, E first off for a slick new shelter when taken on it is treated with acidic and hydrate than the products which have phoned. Should be here in the first case. Orders the product formed. And after that in the second step, one is different. Folks in the first Tepper, we're getting this CST, See? And each is a delicious off. I'm in a group. Mystic in please and got a gun. Great. Brian Henderson here about the plane on below the plane. The group killer is see ej C. It's three. Joyce, choice. This is the group on This is that is too. So this is one as summer. Suppose this is s s alert, then the scene our someone must be using here, so I should be see. It's easy. C o and JJ, see? No. Here ever the bling it should be. See, seeing to rejoice and below the train Hide Rosen harder our contrition. And yet it should be soon it. So this should be our contribution. Oh, to see Mommy knows it. And as edification are this into a media city? Can I trade? This is delicious. Taking this on Dhe Validus treated. Read the second step of this region. We need Peter. Anything. A cell is on dhe by their The product which is formed is, uh, specific girl product is formed. It is, and it's true. And one got one. It is to sewage up. And here, one high treason aboard the plane and your brain seeing. See? So this specific er hi releases is taking place in presence of a Silas. And we are getting the character That is the s I summon This s s summer is in Incheon Monies and Janey Oh, May. So this is the compan formed, and our summer is not undergoing any kind of off this head releases. And, uh, that is way Arkham ponies, regenerative essence and es immer only. We're getting under districts now, in case off B, what is the credit? Phoned so in B The component first phoned by hydrogen in prisons off Kira. Our catalyst here. Marriage Kalitta is a studio specific analyst and in presence of this kind of catalyst, were getting bony specifically one in and Schumer and not the other one on high releases off that train. And Sherman is all you're thinking. It's so by this is the first compartment is formed by hydrogenation. Is seeing Shane c o manage but to key. And here it is a district carbon which is further it is too one hydrogen about the pain and Syria JCO is normally And here it is further at its too o c o c h t So this group is already present One leader at the double bond hydrogenation is sticking this on by this hydrogenation. We're getting this specific in Shima that is the s as in a human, we're getting specifically 100%. And after this when high release it is done in the next The funny part victory be And it's true one dol t four And here again I got one. Then one Henderson is aboard the plane and managed to compute. So this is the specific girl in an Schumer we're getting That is actually yes, I see. Is there a phone in the realization? Now what happens in CID ish? Because of Serie A, Shin begin hydrogenation in presence of piddle orange. Catalyst into says to use the sink analyst is used. And after that, hydrants is so here are so we're expecting the same contribution and the first compartment is formed. Is at this point before the headless is it is starting groaned. You can your destruction and oh, in one born here double bond. And this is further at his tomb one carbon, which is having and it's to group emboldening. You know that clean it is hydrogen and the same thing. See, Lige. So this is at this point you're getting this by the higher education. This company's phoned and by hydra races off the same thing. We're getting the final print and the funny product is this part. No, no, take care because this is not taking part. Dilution here and entreated being seen. And here double one must he did. And this is further and his thing One girl bund in another carbon and discover who should have and it's too and it's too. And one hundreds in here in the village with the product of her illness is on high releases is actually taking place. At this point, that means here, this is not an edge to this should be. You see, Colonel Mustard wasn't here. So is already present in the tent. So clearly in red the easy, which is not distracted by the heavens. Ish so and during the higher illnesses, that means in alkaline hide analyses. And so this, uh, releases is Ticketless here on me and getting the free entry group. So by all the steps, we are getting the specific go in in Schumer. That is the S Isola. And this is yes. Did you go? This is the, you know, silly. It is formed by the CD. She So this is all about result. You shame on dhe thing is a type of resolution in this is this is only we're taking steer specific catalyst. It can be inside, or it can be arranged. Get a list on by that specific amino acids high in sugar can be fault.


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