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PantsConsider the following MO diagram for the hypothetical molecule AZAZPart (Thc bond ordler ol 4Z Is Select Part itAZ I coneIderetl (Selcct ]based on this cliagr...

Question

PantsConsider the following MO diagram for the hypothetical molecule AZAZPart (Thc bond ordler ol 4Z Is Select Part itAZ I coneIderetl (Selcct ]based on this cliagr:UI

Pants Consider the following MO diagram for the hypothetical molecule AZ AZ Part ( Thc bond ordler ol 4Z Is Select Part it AZ I coneIderetl (Selcct ] based on this cliagr:UI



Answers

Write the Levis structure for each molecule. MISSED THIST Read Section 10.7; Watch KCV 10.7, IWE 10.4 a. $\mathrm{SF}_{2}$ b. $\mathrm{SiH}_{4}$ c. HCOOH (both O bonded to C) d. $\mathrm{CH}_{3} \mathrm{SH}$ (C and $\mathrm{S}$ central)

So for this question we have to be atoms and three U. Atoms around the central a. Adam. So we know that the shape will be a tribunal by pyramid als. Since there are five atoms found the central atom. So those give ideal bond angles of 90 degrees and 1 20 degrees. And there's going to be three ways to draw this. So in each case A. Is the central atom. Okay. The first way is that if the bees r 1 80 degrees from each other on one access and the three use on the equatorial axis 123 So this is a 90° angle And this is a 120° angle. But the bees are 180 from each other. The other way to draw. This is to put one B. And one you On the same Axis 1 80° from each other and then to use And be on the equatorial access. Again. This is a 90° angle. This one's 120. And the last way to draw this is to put both of the use on the linear Access here, forming a 1 80° angle The third you will be here. These are 90° apart and The two bees will also be on equatorial axis. So the first one is the ideal structure, since the atoms that are the same are as far apart from each other as possible. So the bees are 1 80 degrees from each other and all of the user all 1 20 degrees from each other. Whereas in these ones, we have bees that are 90 degrees from each other uh and use their 90° from each other. Um in both in this case as well, these are 90° from each other and that is a smaller angle. And we walked the angles to be bigger.

Okay, here we are going toe Pro District, that is asked in a joint. Problem is so this is the structure like this way. Simple oxygen. It, um Then this week. And then this way down this way. And like this. So it looked like that is which. And here, hydro genetic, then here hydrogen atoms. And here, then? Yes. This is extend like this week. Simply say this is which Then head. This is hydrogen and this is which. And here she is again. And this is again which This porch and this hydrogen. So this is the structure off. Collectors! See that stuff off? Bitta? I would grow the secure off collect owes. So see the structure of electors. I would rather secure collectors. Yet it's C, the bulb owned off. Suitable Gondo, then hydrogen. And this carbon, carbon, carbon. So total six. Cartman wanted 2345 and six. But this is C H h. Here. This is a witch hydrogen. And he had more, which and old. So here, hydrogen yet again. Hydrogen. And this is which. And this so we can number is one who see Four life and six God. So this five carbon offset. Genital is attached. It's got what? So it is on a lake. Is this now would draw the secure off dull fog electors. Alfa collectors. So hopefully actors is similar. Similar will be directors. A little difference. We're seeing this stuff. It's his oxygen. Yes, In this way, then this week, Look and extend. This this is look like no here, oxygen it. And this is like yet which in high tops. And this is hydrogen and yeah, which again, this is hydrogen. This is hydrogen. And this is college. Okay, now this group is hydrogen hydrogen, and this is a witch, This hydrogen. And then here is hydrogen. And this is which. That was yesterday. Black toes and see the secure off collectors. This here. Stop. You know, collect Does collectibles. Now see the structure off Alpha and beta like plateaus. See this group at position number one, This is Mission number one. And this. Which group? Position number. Okay, what you upset in these two? Step? See the tag Lactose the Which group is upward. And but Alphago oppose the which group at carbon one position is downwards. So we see that we can see that that difference. The difference between that do safely jet. The difference between that, too. It's like clicks took Jeb's is the audience station. Is the orientation off the ID? Roxanne? A little. That which group on God 11 on. Got anyone on carbon one. Okay, I see. Say this structure. So these doctor are glib idiom with each of them with a black purse, black post and Alfa Gleick toes and alpha collectors. And with Douglas does the difference is only see one position Gartman one position.

The organic compound, and this problem is at the whole, Bromine says. You can see we have a parent compound of two carbons with a bro Ming. And if we're going to go draw some Newman productions, we're gonna look at these two carpet. It's and so the 1st 1 I drew is a anti. You're in projection, and the 2nd 1 on Draw I drew was the Eclipse or SIM production, and so as you can

For part A are molecule consists of one bro Mean long did with five florins. So this is what our structure will look like. Our center Adam will be bro mean And we'll have a floor in tach to vertically and this way, and it may be symmetric. And again, this way. Notice the shapes. These lines represent a three D structure and this kind of solid triangle also represent the three D structure. So what we're saying is that the florins in riel space were in a lab or something like that will actually be in three D. So what this structure is telling us is we have six electron regions, and that means that our geometry is Octa hydro. And we have a sweat, a square per pure middle shape. And now on for part B, we have one sulfur bonded to six chlorine. Again, we'll have a sulfur as our centre Adam and then six Koreans remember, we still have four that are in three D. And again we'll have six electron regions and are geometry and shape will both be Octa. He drollas. Well, now on to part C, we have one phosphorus bonded to five flooring Adams. So our center Adam will be the phosphorus and we'll have five florins. The only thing that's special about this Louis structure is that we have lone pairs on all of our Florian's. And this is because if we look at the periodic table, Florian is much more electro negative than phosphorus. However, flooring also has to obey the octet rule. And because of this increased electro negativity, we'll have these lone pairs on Fleury from Miss Lewis structure, we can see that we have five electron regions, so our shape and geometry will both be triggered. Aled Biker Middle and now onto Part D. This is now an ion. We have one iodine bonded to four florins, and we're going to say this entire molecule has a positive charge. So we're gonna have our one iodine, two flooring Adams and then our other to Florida. Adams will again be quote unquote three D. So what, this is telling us we have five electron groups. We'll have the geometry of a tribunal by pure middle, and our shape will be seesaw


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