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For each the following IR spectra,indicate (on page 1_ the most important stretching signal from the following choices: N-H, 0-H; CEN; C-0,C-0, (1 point each; 2 poi...

Question

For each the following IR spectra,indicate (on page 1_ the most important stretching signal from the following choices: N-H, 0-H; CEN; C-0,C-0, (1 point each; 2 points total) Top, IR spectrum of Compound A: CaHnoOz; Bottom, IR Spectrum of Compound B: CtH:Nz4v00Cmiczo0C10oohatenundtrAuuRoooLsdo1oooHatfnmnatpis

For each the following IR spectra,indicate (on page 1_ the most important stretching signal from the following choices: N-H, 0-H; CEN; C-0,C-0, (1 point each; 2 points total) Top, IR spectrum of Compound A: CaHnoOz; Bottom, IR Spectrum of Compound B: CtH:Nz 4v00 Cmic zo0C 10oo hatenundtr Auu Rooo Lsdo 1ooo Hatfnmnatpis



Answers

Each of the IR spectra shown below is the spectrum of one of the following compounds. Identify the compound that produced each spectrum.

And only by day I asked. Patrol beats each of it. Good morning to you. The first one is 4 19. Too old or 19? 21 one toe, three food fight thinking too old. 1234 I never wanted. Yeah, so if you look at the structure, there is no conjugation and soul beginning. This is an issue. Later, kiddo. Go, which appears at 1715 centimeters. Universe, that is the key to speed. And we won't know adoption this place in my breast now feel everyone over the second car bodies to die middle. Yeah, or he has threes years. Everyone's here. She was here. That is three pending. Too old He thinking too old. Yeah, Here is contribution. So the least contribution on defeat. Off softened. Relax. One thing Age. What is significant votes? The third, um, movies who do die Emulate cycle Abendanon Cyclo Pinned it all to to die Mealtime. This is a prime number. Ring he don't Andi. It appears it so plain emerging. Appears at 17.2. Sending between words. Next, my tiger. Ruben. Guilty hired Windows blown off. Absorption. Uh huh. 170 Quite 170 play. You do see everyone for stretch and then 27 to 0 and 28 to 0 27 20 and to eat do hero absorption due to leave. See it publicly to look. Thank you. What we should we do this absorption? Next come moments like low. Have you? No one? You don't hear just three supplements, you know? So there is no congregation, so it will appeal at 17 One thing Significantly, Waas and the Mexican Bowl is uh yeah, okay to Hexen are to Cinar. 12345 Fix So 284 and everyone. So this is a communicated Tito a convicted and a Alfa Beta unsaturated Randy Haiti. So see, all absorption will be I had 170 plane for contributed idea heads.

So an absorption in the 3000 region indicates that the structure does have hydrogen is present. Not all bonded to SP two hybridized carbons as well as SP three hybridized carbons. When considering all of the given compounds Benzel alcohol on Benzel aiming are the only structures that have SP three carbons. So there is also an observed peak at 3300 which corresponds to our O age group. We do not have an absorption at about 1600 so I'm ruling out the present often an H Therefore, from the data above, I have determined that our structure is in fact Ben Zyl alcohol So we can simply draw this out below. Start off with our benzene ring With all of the three of the conjugated bonds, we have a CH two and then an O. H

Absorption that we see at 1600 wave numbers on 15 hundreds of 14. 30. We've numbers indicate that the compound we're looking at toe identify maybe a benzene ring. So we also see an absorption of 3000. So this suggests that we have hydrogen attached to SP two hybridized carbons, not SP three hybridized carbons. So the absence off any sort of absorption of 1700 suggest that we do not have any carbon. Are groups present here? So for the above need reasoning, we may have a female so weaken simply just draw out our penal structure. Well, we can identify our functional groups where we have our benzene ring should R c six h six and we can draw on all functional group which is our alcohol on any given carbon because it's money substituted, it doesn't matter. We always assume that the carbon that are substitution is on. In a mono substituted structure is carbon one

Yeah, The problem. Number 79 to calm bombs. Who's Yeah, Tomorrow on my hospital values and even inspectors anyone? They had to identify them. Hubble's last one empress is 114 114 Andi, The other signals 71 who killed 43 in 27 40 days. Obey. Speak 27. Yeah. Choose a kid. A group due to the 1700 signal animal foods. Mhm. Things to do is to two protons with this one on. This is a triplet and multiply it on a little plate on this value the doctor value on the speakers around 2.3, indicating it is attached where he took group. So this should be Is he? It's three c x two. See? It's too group. They should be arrested with a group. If we can calculate the mass of the world is we'll find that this is, uh, 15 girls 79. Plus this is 43 43 breasts. Mhm. It will be totally 71. So 100 Total value. 114 minus 71. It's three. What is leaving, which with no other signals we can Controlling that. This it is a symmetric molecule with exactly the same order, they said. Also, see a student safety, of course. No, not everyone suburban, the second commonly having a mask when you have 1 54 on there is an implicit too big at 1 46. On the peak is approximately one third of the Empress speak, indicating it is seclusion at convincing crooner's. Certainly the I ask Spectrum Shoes Excellent at 1700 indicative of the Taliban a group. And there is no striking revelation of C H in the range, UH, 2700 something showing that it is not an alligator Animals that reinforces English anymore shows single it, but four point seven $4.7 is English off to each. That means that program should be. It is so long field for points. Having square downfield, she has to sing like means that this year's too much filters to win extraordinary. The other animal signals are those of dramatic 7.6 to 8 winter. There are quite programs in this region in the ratio do is to do is tow one. That means it should be more often people debating now recalling all these together. You get this culture on the molecule. See everyone home. C h two. Yeah. This is the Yes. The month spectrum contains very speak of 105. This corresponds to this part of you, Marty, which is called stabilizers, right? It's got a ideas, similar agency or group. So this is the structure of the molecule.


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